1,1,4,7,10,10-Hexamethyltriethylenetetramine, 97%, Thermo Scientific Chemicals

Description

1,1,4,7,10,10-Hexamethyltriethylenetetramine may be used as reagent in the synthesis of ideal linear random copolymers containing both vinyl polymer and polyester units in a single polymer chain.1 1,1,4,7,10,10-Hexamethyltriethylenetetramine complexed with CuBr constitutes catalytic complex, used in the copolymerization of poly[ε-caprolactone] with N,N-dimethylamino-2-ethyl methacrylate monomers by atom-transfer radical polymerization (ATRP).2 It may be used as catalyst in the aqueous surface-initiated-ATRP to grow poly(N,N-dimethylacrylamide) (PDMA).3

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1,1,4,7,10,10-Hexamethyltriethylenetetramine may be used as reagent in the synthesis of ideal linear random copolymers containing both vinyl polymer and polyester units in a single polymer chain.1 1,1,4,7,10,10-Hexamethyltriethylenetetramine complexed with CuBr constitutes catalytic complex, used in the copolymerization of poly[ε-caprolactone] with N,N-dimethylamino-2-ethyl methacrylate monomers by atom-transfer radical polymerization (ATRP).2 It may be used as catalyst in the aqueous surface-initiated-ATRP to grow poly(N,N-dimethylacrylamide) (PDMA).3

Solubility
Soluble in water.

Notes
Incompatible with oxidizing agents. Store at room temperature.

Specifications

Chemical Identifiers

• CAS: 3083-10-1
• MDL Number: MFCD00025684

• Density: 0.847
• Boiling Point: 130°C (11 mmHg)
• Flash Point: 102°C (216°F)
• Molecular Formula: C7H6N2O2S
• Refractive Index: 1.456
• Quantity: 5 g
• UN Number: UN3725
• Synonym: 4-cyanobenzene-1-sulfonamide, p-cyanobenzenesulfonamide, 4-cyanobenzenesulphonamide, benzenesulfonamide, p-cyano, 4-cyano-benzenesulfonamide, benzenesulfonamide, 4-cyano, p-cyanobenzenesulphonamide, benzenesulfonamide, 4-cyano-9ci, 4-sulphamoylbenzonitrile, wln: zswr dcn
• Solubility Information: Soluble in water.
• InChI Key: UZECCNDOASGYNH-UHFFFAOYSA-N
• SMILES: C1=CC(=CC=C1C#N)S(=O)(=O)N
• IUPAC Name: 4-cyanobenzenesulfonamide
• Molecular Weight (g/mol): 182.20
• PubChem CID: 76566
• Formula Weight: 230.39
• Percent Purity: 97%
• Chemical Name or Material: 1,1,4,7,10,10-Hexamethyltriethylenetetramine

Safety and Handling

Product Identifier

• 1,1,4,7,10,10-Hexamethyltriethylenetetramine

Signal Word

• Danger

Hazard Category

• Serious eye damage/eye irritation Category 1
• Skin corrosion/irritation Category 1 B

Hazard Statement

• H314-Causes severe skin burns and eye damage.
• H318-Causes serious eye damage.

Precautionary Statement

• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.

Supplemental information

• MIXTURE LIST-Contains : N,N-bis[2-(dimethylamino)ethyl]-N,N-dimethyl-1,2-Ethanediamine

RUO – Research Use Only