1,1'-Bis(diisopropylphosphino)ferrocene, 98%, Thermo Scientific Chemicals

Description

The general and efficient cross-coupling of thiols with aryl halides was developed utilizing Pd(OAc) 2 /1,1-bis(diisopropylphosphino)ferrocene as the catalyst. The oxidative electrochemistry of dippf was examined, and it was found to follow an ECDim mechanism. Seven new compounds containing dippf were prepared and characterized spectroscopically. The crystal structures of [MCl2(dippf)] (M = Pt and Zn) were determined.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
The general and efficient cross-coupling of thiols with aryl halides was developed utilizing Pd(OAc) 2 /1,1′-bis(diisopropylphosphino)ferrocene as the catalyst. The oxidative electrochemistry of dippf was examined, and it was found to follow an ECDim mechanism. Seven new compounds containing dippf were prepared and characterized spectroscopically. The crystal structures of [MCl2(dippf)] (M = Pt and Zn) were determined.

Solubility
Insoluble in water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Specifications

Chemical Identifiers

• CAS: 97239-80-0
• Molecular Formula: C22H36FeP2
• Molecular Weight (g/mol): 418.32
• MDL Number: MFCD02684559
• IUPAC Name: 1,1'-Bis(diisopropylphosphino)ferrocene
• SMILES: [Fe].CC(C)P(C(C)C)c1cccc1.CC(C)P(C(C)C)c1cccc1

• Melting Point: 50°C to 52°C
• Flash Point: >110°C (230°F)
• Quantity: 1 g
• Solubility Information: Insoluble in water.
• Formula Weight: 418.34
• Percent Purity: 98%
• Chemical Name or Material: 1,1'-Bis(diisopropylphosphino)ferrocene

Safety and Handling

Product Identifier

• 1,1'-Bis(diisopropylphosphino)ferrocene

Signal Word

• Warning

Hazard Category

• Acute toxicity Category 4
• Serious eye damage/eye irritation Category 2
• Skin corrosion/irritation Category 2
• Specific target organ toxicity Category 3

Hazard Statement

• H302-Harmful if swallowed.
• H315-Causes skin irritation.
• H319-Causes serious eye irritation.
• H335-May cause respiratory irritation.

Precautionary Statement

• P261-Avoid breathing dust/fume/gas/mist/vapours/spray.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P312-IF SWALLOWED: Call a POISON CENTER or doctor/physician/ if you feel unwell.
• P302+P352-IF ON SKIN: Wash with plenty of water/soap.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Supplemental information

• MIXTURE LIST-Contains : 1,1-Bis(diisopropylphosphino)ferrocene

RUO – Research Use Only