1,1'-Bis(diphenylphosphino)ferrocene, 97%, Thermo Scientific Chemicals

Product Code	Brand	Quantity
11454657	Thermo Scientific Alfa Aesar B21166.03	1 g
11464657	Thermo Scientific Alfa Aesar B21166.06	5 g
11474657	Thermo Scientific Alfa Aesar B21166.14	25 g

Description

1,1'-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for palladium-catalyzed coupling reactions and also plays an important role in Suzuki reaction.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1,1′-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for palladium-catalyzed coupling reactions and also plays an important role in Suzuki reaction.

Solubility
Soluble in chloroform, dichloromethane, alcohol and pentane. Insoluble in water.

Notes
Air sensitive. Store in a cool place. Incompatible with strong oxidizing agents.

Chemical Identifiers

• CAS: 12150-46-8
• Molecular Weight (g/mol): 554.39
• InChI Key: KZPYGQFFRCFCPP-UHFFFAOYSA-N
• SMILES: [Fe].c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1.c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1

• Molecular Formula: C34H28FeP2
• MDL Number: MFCD00001422
• IUPAC Name: λ²-iron(2+) bis(1-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide)

Specifications

• CAS: 12150-46-8
• Assay Percent Range: 0.97
• MDL Number: MFCD00001422
• Solubility Information: Soluble in chloroform,dichloromethane,alcohol and pentane. Insoluble in water.
• SMILES: [Fe].c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1.c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1
• Molecular Weight (g/mol): 554.39
• Percent Purity: 97%

• Melting Point: ∽182°C (decomposition)
• Molecular Formula: C34H28FeP2
• Sensitivity: Air sensitive
• InChI Key: KZPYGQFFRCFCPP-UHFFFAOYSA-N
• IUPAC Name: λ²-iron(2+) bis(1-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide)
• Formula Weight: 554.4
• Chemical Name or Material: 1, 1'-Bis(diphenylphosphino)ferrocene

Safety and Handling

GHS H Statement
H315-H319-H335

P261-P264b-P270-P271-P280-P301+P310-P302+P352-P304+P340-P312-P330-P363-P501c

H301-H312-H332

missing translation for 'dotInformation' : Hazard Class: 6.1; Packaging Group: III

missing translation for 'tsca' : No

missing translation for 'storageNote' : Air Sensitive

Recommended Storage : Keep cold; Store under Argon

RUO – Research Use Only