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  6. 1,1'-Bis(diphenylphosphino)ferrocene, 97%, Thermo Scientific Chemicals

1,1'-Bis(diphenylphosphino)ferrocene, 97%, Thermo Scientific Chemicals

Product Code. 11454657
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1 g
5 g
25 g
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Regulatory: Restrictions may apply to the purchase of this product and we may need to request additional documentation from you

Description

1,1'-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for palladium-catalyzed coupling reactions and also plays an important role in Suzuki reaction.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1,1′-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for palladium-catalyzed coupling reactions and also plays an important role in Suzuki reaction.

Solubility
Soluble in chloroform, dichloromethane, alcohol and pentane. Insoluble in water.

Notes
Air sensitive. Store in a cool place. Incompatible with strong oxidizing agents.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 12150-46-8
Molecular Formula C34H28FeP2
Molecular Weight (g/mol) 554.39
MDL Number MFCD00001422
InChI Key KZPYGQFFRCFCPP-UHFFFAOYSA-N
IUPAC Name λ²-iron(2+) bis(1-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide)
SMILES [Fe].c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1.c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1

Specifications

Melting Point ∽182°C (decomposition)
Assay Percent Range 0.97
Quantity 1 g
Sensitivity Air sensitive
Solubility Information Soluble in chloroform,dichloromethane,alcohol and pentane. Insoluble in water.
Formula Weight 554.4
Percent Purity 97%
Chemical Name or Material 1, 1'-Bis(diphenylphosphino)ferrocene

RUO – Research Use Only

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