1,1'-Bis(diphenylphosphino)ferrocene, 97%, Thermo Scientific Chemicals

Description

1,1'-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for palladium-catalyzed coupling reactions and also plays an important role in Suzuki reaction.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1,1′-Bis(diphenylphosphino)ferrocene acts as a ligand in homogeneous catalysis. It is used as a ligand for ruthenium-catalyzed greener amine synthesis from amines and alcohols by hydrogen-borrowing. It is also employed as a ligand for Buchwald-Hartwig cross coupling. Further, it is used in the synthesis of coordination compound as well as the formation of complexes with various metals such as palladium chloride. In addition to this, it serves as a reagent for palladium-catalyzed coupling reactions and also plays an important role in Suzuki reaction.

Solubility
Soluble in chloroform, dichloromethane, alcohol and pentane. Insoluble in water.

Notes
Air sensitive. Store in a cool place. Incompatible with strong oxidizing agents.

Specifications

Chemical Identifiers

• CAS: 12150-46-8
• Molecular Formula: C34H28FeP2
• Molecular Weight (g/mol): 554.39
• MDL Number: MFCD00001422
• InChI Key: KZPYGQFFRCFCPP-UHFFFAOYSA-N
• IUPAC Name: λ²-iron(2+) bis(1-(diphenylphosphanyl)cyclopenta-2,4-dien-1-ide)
• SMILES: [Fe].c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1.c1ccc(c1)P(C1=CC=CC=C1)C1=CC=CC=C1

• Melting Point: ∼182°C (decomposition)
• Assay Percent Range: 0.97
• Quantity: 25 g
• Sensitivity: Air sensitive
• Synonym: Dppf, 1,1'-Ferrocenebis(diphenylphosphine)
• Solubility Information: Soluble in chloroform,dichloromethane,alcohol and pentane. Insoluble in water.
• Formula Weight: 554.4
• Percent Purity: 97%
• Chemical Name or Material: 1,1'-Bis(diphenylphosphino)ferrocene

Safety and Handling

Product Identifier

• 1,1'-Bis(diphenylphosphino)ferrocene

Signal Word

• Danger

Hazard Category

• Acute toxicity Category 3

Hazard Statement

• H301-Toxic if swallowed.

Precautionary Statement

• P264-Wash face, hands and anyexposed skin thoroughly after handling.
• P270-Do not eat, drink or smoke when using this product.
• P301+P310-IF SWALLOWED: Immediately call a POISON CENTER/doctor /
• P330-Rinse mouth.
• P405-Store locked up.
• P501b-Dispose of contents/container in accordance with local/regional/national/international regulations.

Supplemental information

• MIXTURE LIST-Contains : 1,1'-Bis(diphenylphosphino)ferrocene

RUO – Research Use Only