1-Methylpiperidine, 99%, Thermo Scientific Chemicals

Product Code	Brand	Quantity
11332136	Thermo Scientific Alfa Aesar L03398.09	10 g
11342136	Thermo Scientific Alfa Aesar L03398.22	100 g
11352136	Thermo Scientific Alfa Aesar L03398.36	500 g

Description

1-Methylpiperidine is a reactant for sp3 C-H Bond activation with ruthenium(II) catalysts and C(3)-alkylation of cyclic amines, One-pot synthesis of Z-cinnamic acids. It is used in the synthesis of Unsymmetrical ureas, Antibacterial imidazolium, pyrrolidinium, and piperidinium salts, C1-C16 segment of goniodomin A via palladium-catalyzed organostannane thioester coupling.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
1-Methylpiperidine is a reactant for sp3 C-H Bond activation with ruthenium(II) catalysts and C(3)-alkylation of cyclic amines, One-pot synthesis of Z-cinnamic acids. It is used in the synthesis of Unsymmetrical ureas, Antibacterial imidazolium, pyrrolidinium, and piperidinium salts, C1-C16 segment of goniodomin A via palladium-catalyzed organostannane thioester coupling.

Solubility
Fully miscible in water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with.acids, Acid chlorides, Acid anhydrides, Strong oxidizing agents, Carbon dioxide.

Chemical Identifiers

• CAS: 626-67-5
• Molecular Weight (g/mol): 135.64
• InChI Key: QDUXDCXILAPLAG-UHFFFAOYSA-N
• PubChem CID: 12291
• SMILES: [H+].[Cl-].CN1CCCCC1

• Molecular Formula: C6H14ClN
• MDL Number: MFCD00006491
• Synonym: n-methylpiperidine, piperidine, 1-methyl, methylpiperidine, n-methyl piperidine, 1-methyl-piperidine, n-methylpiperidin, methylpiperdine, 1-methylpiperadine, n-methyl-piperidine, 1-methyl piperidine
• IUPAC Name: 1-methylpiperidine

Specifications

• CAS: 626-67-5
• Density: 0.816
• Boiling Point: 105°C to 107°C
• Odor: Amine-like
• Refractive Index: 1.4378
• UN Number: UN2399
• Synonym: n-methylpiperidine, piperidine, 1-methyl, methylpiperidine, n-methyl piperidine, 1-methyl-piperidine, n-methylpiperidin, methylpiperdine, 1-methylpiperadine, n-methyl-piperidine, 1-methyl piperidine
• InChI Key: QDUXDCXILAPLAG-UHFFFAOYSA-N
• IUPAC Name: 1-methylpiperidine
• PubChem CID: 12291
• Percent Purity: 99%

• Melting Point: -50°C
• pH: 12
• Flash Point: 3°C (37°F)
• Molecular Formula: C6H14ClN
• MDL Number: MFCD00006491
• Beilstein: 1073
• Solubility Information: Fully miscible in water.
• SMILES: [H+].[Cl-].CN1CCCCC1
• Molecular Weight (g/mol): 135.64
• Formula Weight: 99.18
• Chemical Name or Material: 1-Methylpiperidine

Safety and Handling

GHS H Statement
H225-H331-H314-H318-H302
Highly flammable liquid and vapor.
Toxic if inhaled.
Causes severe skin burns and eye damage.
Causes serious eye damage.
Harmful if swallowed.

P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

H225-H302+H312+H332-H314-H335

missing translation for 'dotInformation' : Transport Hazard Class: 3; Packing Group: II; Proper Shipping Name: 1-METHYLPIPERIDINE

missing translation for 'einecsNumber' : 210-959-9

missing translation for 'rtecsNumber' : TN1225000

missing translation for 'tsca' : Yes

Recommended Storage : Ambient temperatures

RUO – Research Use Only