(1S)-(-)-Camphanic chloride, 95%, Thermo Scientific Chemicals

Description

(1S)-(-)-Camphanic chloride is used as a resolving agent for alcohols as the diastereomeric esters by crystallization or chromatography and as a chiral derivatization reagent for determination of enantiomeric excess of alcohols and amines.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
(1S)-(-)-Camphanic chloride is used as a resolving agent for alcohols as the diastereomeric esters by crystallization or chromatography and as a chiral derivatization reagent for determination of enantiomeric excess of alcohols and amines.

Solubility
Soluble in dichloromethane, ether, ethyl acetate and methanol. Reacts with water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Recommended storage temperature is 2 - 8°C. Store under inert gas. It is sensitive to moisture. Protect from humidity and water. Incompatible with bases and oxidizing agents.

Specifications

Chemical Identifiers

• CAS: 39637-74-6
• Molecular Formula: C10H13ClO3
• Molecular Weight (g/mol): 216.661
• MDL Number: MFCD00135626
• InChI Key: PAXWODJTHKJQDZ-QVDQXJPCSA-N
• Synonym: 1s-4,7,7-trimethyl-3-oxo-2-oxabicyclo 2.2.1 heptane-1-carbonyl chloride, --1s,4r-camphanoyl chloride, 1s---camphanic acid chloride
• PubChem CID: 12364938
• IUPAC Name: (4S)-1,7,7-trimethyl-2-oxo-3-oxabicyclo[2.2.1]heptane-4-carbonyl chloride
• SMILES: CC1(C2(CCC1(OC2=O)C(=O)Cl)C)C

• Melting Point: 64°C to 68°C
• Quantity: 1 g
• UN Number: UN3261
• Beilstein: 3590860
• Sensitivity: Moisture sensitive
• Solubility Information: Soluble in dichloromethane,ether,ethyl acetate and methanol. Reacts with water.
• Optical Rotation: −18° (c=2 in Carbon Tetrachloride)
• Formula Weight: 216.67
• Percent Purity: 95%
• Chemical Name or Material: (1S)-(-)-Camphanic chloride

RUO – Research Use Only