3-(Methoxycarbonyl)benzeneboronic acid, 97%, Thermo Scientific Chemicals

Product Code	Brand	Quantity
11387289	Thermo Scientific Alfa Aesar H27444.03	1 g
11397289	Thermo Scientific Alfa Aesar H27444.06	5 g

Description

Reagent used for tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence, copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides, one-pot ipso-nitration of arylboronic acids, copper-catalyzed nitration, cyclocondensation followed by palladium-phosphine-catalyzed Suzuki-Miyaura coupling. Reagent used in Preparation of biaryls via nickel-catalyzed Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acid6, chromenones and their bradykinin B1 antagonistic active, Pt nanoparticles at Photoactive metal-organic frameworks resulting in efficient hydrogen evolution via synergistic photoexcitation and electron injecti, salicylate-based thienylbenzoic acids as E. coli methionine aminopeptidase inhibitor.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Reagent used for tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence, copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides, one-pot ipso-nitration of arylboronic acids, copper-catalyzed nitration, cyclocondensation followed by palladium-phosphine-catalyzed Suzuki-Miyaura coupling. Reagent used in Preparation of biaryls via nickel-catalyzed Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acid6, chromenones and their bradykinin B1 antagonistic active, Pt nanoparticles at Photoactive metal-organic frameworks resulting in efficient hydrogen evolution via synergistic photoexcitation and electron injecti, salicylate-based thienylbenzoic acids as E. coli methionine aminopeptidase inhibitor.

Solubility
Reacts with water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Chemical Identifiers

• CAS: 99769-19-4
• Molecular Weight (g/mol): 179.97
• InChI Key: ALTLCJHSJMGSLT-UHFFFAOYSA-N
• PubChem CID: 2734714

• Molecular Formula: C8H9BO4
• MDL Number: MFCD02093046
• Synonym: 3-methoxycarbonyl phenylboronic acid, 3-methoxycarbonylphenyl boronic acid, 3-methoxycarbonyl phenyl boronic acid, 3-methoxycarbonyl benzeneboronic acid, 3-methoxycarbonylphenylbaronic acid, methyl 3-dihydroxyboranyl benzoate, m-methoxycarbonyl phenylboronic acid, 3-carbomethoxy-phenylboronic acid
• SMILES: COC(=O)C1=CC=CC(=C1)B(O)O

Specifications

• CAS: 99769-19-4
• Molecular Formula: C8H9BO4
• Synonym: 3-methoxycarbonyl phenylboronic acid, 3-methoxycarbonylphenyl boronic acid, 3-methoxycarbonyl phenyl boronic acid, 3-methoxycarbonyl benzeneboronic acid, 3-methoxycarbonylphenylbaronic acid, methyl 3-dihydroxyboranyl benzoate, m-methoxycarbonyl phenylboronic acid, 3-carbomethoxy-phenylboronic acid
• InChI Key: ALTLCJHSJMGSLT-UHFFFAOYSA-N
• IUPAC Name: [3-(methoxycarbonyl)phenyl]boronic acid
• PubChem CID: 2734714
• Percent Purity: 97%

• Melting Point: 136°C
• MDL Number: MFCD02093046
• Solubility Information: Reacts with water.
• SMILES: COC(=O)C1=CC=CC(=C1)B(O)O
• Molecular Weight (g/mol): 179.97
• Formula Weight: 179.97
• Chemical Name or Material: 3-(Methoxycarbonyl)benzeneboronic acid

Safety and Handling

GHS H Statement
H315-H319-H335
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

H315-H319-H335

missing translation for 'tsca' : No

Recommended Storage : Ambient temperatures

RUO – Research Use Only