3-Methoxyphenylmagnesium bromide, 1M solution in THF/toluene, AcroSeal™, Thermo Scientific Chemicals

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Specifications

Chemical Identifiers

• CAS: 36282-40-3, 109-99-9, 108-88-3
• Molecular Formula: C7H7BrMgO
• Molecular Weight (g/mol): 211.34
• MDL Number: MFCD00672002
• InChI Key: AJKNYEHIJAMGHX-UHFFFAOYSA-M
• Synonym: 3-methoxyphenylmagnesium bromide, 3-methoxyphenyl magnesium bromide, 3-methoxyphenylmagnesium bromide solution, 3-methoxyphenylmagnesiumbromide, 3-methoxyphenylmagnesiumbromid, bromo 3-methoxyphenyl magnesium, 3-methoxy phenylmagnesium bromide, 3-methoxyphenyl-magnesium bromide, m-methoxyphenyl magnesium bromide, 3-methoxylphenyl magnesium bromide, grignard reagent
• PubChem CID: 4605969
• SMILES: COC1=CC=CC([Mg]Br)=C1

• CAS Min %: 19.02, 76.75
• CAS Max %: 23.25, 80.98
• Color: Yellow to Brown
• Density: 1.0000g/mL
• Flash Point: −21°C
• Packaging: AcroSeal™ Glass bottle
• Linear Formula: CH₃OC₆H₄MgBr
• Quantity: 100 mL
• UN Number: 2924
• Specific Gravity: 1
• IUPAC Name: magnesium;methoxybenzene;bromide
• Formula Weight: 211.34
• Physical Form: Solution
• Chemical Name or Material: 3-Methoxyphenylmagnesium bromide, 1M solution in THF/toluene

Safety and Handling

Product Identifier

• 3-Methoxyphenylmagnesium bromide, 1M solution in THF/toluene

Signal Word

• Danger

Hazard Category

• Aspiration toxicity Category 1
• Carcinogenicity Category 2
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 2
• Reproductive toxicity Category 2
• Skin corrosion/irritation Category 1 B
• Specific target organ toxicity after repeated exposure Category 2
• Specific target organ toxicity Category 3

Hazard Statement

• H304-May be fatal if swallowed and enters airways.
• H318-Causes serious eye damage.
• H314-Causes severe skin burns and eye damage.
• H351-Suspected of causing cancer.
• H361d-Suspected of damaging the unborn child.
• H373-May cause damage to organs.
• H335-May cause respiratory irritation.
• H336-May cause drowsiness or dizziness.
• H225-Highly flammable liquid and vapour.
• EUH014-Reacts violently with water.
• EUH019-May form explosive peroxides.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.

RUO – Research Use Only