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4-Bromo-4'-hydroxybiphenyl, 98%, Thermo Scientific Chemicals

Product Code. 11439762
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Quantity:
5 g
25 g
100 g
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A biphenyl starting material. 4-Bromo-(1,1-biphenyl)-4-ol is a useful intermediate. Vinylation of 4-bromo-4-hydroxybiphenyl and ethyl acrylate using Pd (OAc) 2/PPh 3 catalyst was studied. Ethyl 4-(4-hydroxyphenyl) cinnamate was formed as the vinylation product, while, 4-hydroxybiphenyl and ethyl cinnamate were formed as side products. Preparation of 4-cyano-4'-hydroxybiphenyl This was prepared from 4-bromo-4'-benzenesulphonyloxybiphenyl by first hydrolysing it to 4-bromo-4-hydroxybiphenyl using sodium hydroxide dissolved in a mixture of water and dioxan. The syntheses of the Nanocomposite dendrimers based on cyclic phosphazene cores: Amorphous materials, were accomplished by following a modified literature procedure by reacting phosphonitrilic chloride trimer with 4-bromophenol or 4-bromo-4-hydroxybiphenyl, respectively, in the presence of K 2 CO 3 in tetrahydrofuran (THF).

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
A biphenyl starting material. 4′-Bromo-(1,1′-biphenyl)-4-ol is a useful intermediate. Vinylation of 4-bromo-4′-hydroxybiphenyl and ethyl acrylate using Pd (OAc) 2/PPh 3 catalyst was studied. Ethyl 4-(4′-hydroxyphenyl) cinnamate was formed as the vinylation product, while, 4-hydroxybiphenyl and ethyl cinnamate were formed as side products. Preparation of 4-cyano-4′-hydroxybiphenyl This was prepared from 4-bromo-4′-benzenesulphonyloxybiphenyl by first hydrolysing it to 4-bromo-4-hydroxybiphenyl using sodium hydroxide dissolved in a mixture of water and dioxan. The syntheses of the Nanocomposite dendrimers based on cyclic phosphazene cores: Amorphous materials, were accomplished by following a modified literature procedure by reacting phosphonitrilic chloride trimer with 4-bromophenol or 4-bromo-4′-hydroxybiphenyl, respectively, in the presence of K 2 CO 3 in tetrahydrofuran (THF).

Solubility
Soluble in water (partly), and methanol.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 29558-77-8
Molecular Formula C12H9BrO
Molecular Weight (g/mol) 249.107
MDL Number MFCD00059076
InChI Key ARUBXNBYMCVENE-UHFFFAOYSA-N
Synonym 4-bromo-4'-hydroxybiphenyl, 4'-bromo-1,1'-biphenyl-4-ol, 4-4-bromophenyl phenol, 4'-bromobiphenyl-4-ol, 4-hydroxy-4'-bromobiphenyl, 1,1'-biphenyl-4-ol, 4'-bromo, 4-bromo-4-hydroxybiphenyl, pubchem23025
PubChem CID 95093
IUPAC Name 4-(4-bromophenyl)phenol
SMILES C1=CC(=CC=C1C2=CC=C(C=C2)Br)O

Specifications

Melting Point 163°C to 168°C
Quantity 5 g
Solubility Information Soluble in water (partly),and methanol.
Formula Weight 249.11
Percent Purity 98%
Chemical Name or Material 4-Bromo-4'-hydroxybiphenyl

RUO – Research Use Only

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