4-Bromobutyronitrile, 97%, Thermo Scientific Chemicals

Product Code	Brand	Quantity
11413434	Thermo Scientific Alfa Aesar A10674.09	10 g
11423434	Thermo Scientific Alfa Aesar A10674.18	50 g
11433434	Thermo Scientific Alfa Aesar A10674.30	250 g

Description

4-bromobutyronitrile is used as a precursor for the preparation of cylopropyl cyanide. Its derivative, 4-Bromo-2,2-Diphenyl Butyronitrile is used as an intermediate for loperamide.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
4-bromobutyronitrile is used as a precursor for the preparation of cylopropyl cyanide. Its derivative, 4-Bromo-2,2-Diphenyl Butyronitrile is used as an intermediate for loperamide.

Solubility
Miscible with toluene and benzene. Immiscible with water.

Notes
Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong acids, strong bases, strong oxidizing agents and strong reducing agents.

Chemical Identifiers

• CAS: 5332-06-9
• Molecular Weight (g/mol): 148.00
• InChI Key: CQPGDDAKTTWVDD-UHFFFAOYSA-N
• PubChem CID: 21412
• SMILES: C(CC#N)CBr

• Molecular Formula: C4H6BrN
• MDL Number: MFCD00001971
• Synonym: 4-bromobutyronitrile, butanenitrile, 4-bromo, 1-bromo-3-cyanopropane, 3-bromopropyl cyanide, 3-cyanopropyl bromide, gamma-bromobutyronitrile, butyronitrile, 4-bromo, usaf do-6, 4-bromo butyronitrile, trimethylene bromocyanide
• IUPAC Name: 4-bromobutanenitrile

Specifications

• CAS: 5332-06-9
• Boiling Point: 204°C to 206°C
• Odor: Odorless
• Refractive Index: 1.478
• UN Number: UN3276
• Synonym: 4-bromobutyronitrile, butanenitrile, 4-bromo, 1-bromo-3-cyanopropane, 3-bromopropyl cyanide, 3-cyanopropyl bromide, gamma-bromobutyronitrile, butyronitrile, 4-bromo, usaf do-6, 4-bromo butyronitrile, trimethylene bromocyanide
• InChI Key: CQPGDDAKTTWVDD-UHFFFAOYSA-N
• IUPAC Name: 4-bromobutanenitrile
• PubChem CID: 21412
• Percent Purity: 97%

• Density: 1.491
• Flash Point: 103°C (217°F)
• Molecular Formula: C4H6BrN
• MDL Number: MFCD00001971
• Beilstein: 956577
• Solubility Information: Miscible with toluene and benzene. Immiscible with water.
• SMILES: C(CC#N)CBr
• Molecular Weight (g/mol): 148.00
• Formula Weight: 148.01
• Chemical Name or Material: 4-Bromobutyronitrile

Safety and Handling

GHS H Statement
H302-H312-H332-H315-H319
Harmful if swallowed.
Harmful in contact with skin.
Harmful if inhaled.
Causes skin irritation.
Causes serious eye irritation.

P261-P264b-P270-P271-P280-P301+P312-P302+P352-P304+P340-P312-P330-P363-P501c

H302+H312+H332

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missing translation for 'tsca' : Yes

Recommended Storage : Keep cold

Signal Word

• Danger

Hazard Category

• Acute toxicity Category 3
• Serious eye damage/eye irritation Category 2
• Skin corrosion/irritation Category 2
• Specific target organ toxicity Category 3

Hazard Statement

• H301-Toxic if swallowed.
• H311-Toxic in contact with skin.
• H315-Causes skin irritation.
• H319-Causes serious eye irritation.
• H331-Toxic if inhaled.
• H335-May cause respiratory irritation.

Precautionary Statement

• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P302+P352-IF ON SKIN: Wash with plenty of water/.
• P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P311-Call a POISON CENTER/doctor/ .

RUO – Research Use Only