Allyl bromide, 99%, stab. with 300-1000ppm Propylene oxide, Thermo Scientific Chemicals

Product Code	Brand	Quantity
11429333	Thermo Scientific Alfa Aesar A11766.30	250 g
11419333	Thermo Scientific Alfa Aesar A11766.0B	1000 g

Description

Allyl bromide is used as an alkylating agent in the synthesis of pharmaceuticals, polymers, adhesives, perfumes, biochemicals and other allylic compounds. It is used as precursor for the preparation of allyliczinc bromide by reacting it with zinc. It is also used in the preparation of allylethers like allyl decyl ether, allyl benzyl ether and allyl geranyl ether. It is also used in the preparation of R enantiomer of allyl phenyl carbinol (APC) such as 1-phenyl-3-butene, which is a valuable intermediate for drugs and agro-chemicals.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Allyl bromide is used as an alkylating agent in the synthesis of pharmaceuticals, polymers, adhesives, perfumes, biochemicals and other allylic compounds. It is used as precursor for the preparation of allyliczinc bromide by reacting it with zinc. It is also used in the preparation of allylethers like allyl decyl ether, allyl benzyl ether and allyl geranyl ether. It is also used in the preparation of R enantiomer of allyl phenyl carbinol (APC) such as 1-phenyl-3-butene, which is a valuable intermediate for drugs and agro-chemicals.

Solubility
Slightly miscible with water.

Notes
Moisture and light sensitive. Incompatible with oxidizing agents, alkali metals, alkaline earth metals, amides, amines and powdered metals.

Chemical Identifiers

• CAS: 106-95-6
• Molecular Weight (g/mol): 120.977
• InChI Key: BHELZAPQIKSEDF-UHFFFAOYSA-N
• PubChem CID: 7841
• SMILES: C=CCBr

• Molecular Formula: C3H5Br
• MDL Number: MFCD00000244
• Synonym: allyl bromide, 3-bromopropene, 1-propene, 3-bromo, 3-bromopropylene, 3-bromo-1-propene, bromallylene, 2-propenyl bromide, 1-bromo-2-propene, propene, 3-bromo, allylbromide
• IUPAC Name: 3-bromoprop-1-ene

Specifications

• CAS: 106-95-6
• Density: 1.398
• Flash Point: -2°C (28°F)
• Molecular Formula: C3H5Br
• Refractive Index: 1.47
• UN Number: UN1099
• Merck Index: 14,288
• Solubility Information: Slightly miscible with water.
• SMILES: C=CCBr
• Molecular Weight (g/mol): 120.977
• Formula Weight: 120.98
• Physical Form: Liquid

• Melting Point: °C to 119°C
• Boiling Point: 70°C to 71°C
• Assay Percent Range: 99%
• Linear Formula: CH₂=CHCH₂Br
• MDL Number: MFCD00000244
• Sensitivity: Light sensitive
• Synonym: allyl bromide, 3-bromopropene, 1-propene, 3-bromo, 3-bromopropylene, 3-bromo-1-propene, bromallylene, 2-propenyl bromide, 1-bromo-2-propene, propene, 3-bromo, allylbromide
• InChI Key: BHELZAPQIKSEDF-UHFFFAOYSA-N
• IUPAC Name: 3-bromoprop-1-ene
• PubChem CID: 7841
• Percent Purity: 99%
• Chemical Name or Material: Allyl Bromide, Stabilized with 300 to 1000ppm Propylene oxide

Safety and Handling

GHS H Statement
H225-H301-H331-H340-H350-H314

P201-P202-P210-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P281-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P370+P378q-P501c

H225-H301+H331-H314-H335-H340-H350

missing translation for 'dotInformation' : Transport Hazard Class: 3; Packing Group: I; Proper Shipping Name: ALLYL BROMIDE

missing translation for 'einecsNumber' : 203-446-6

missing translation for 'rtecsNumber' : UC7090000

missing translation for 'tsca' : Yes

Recommended Storage : Ambient temperatures

Product Identifier

• Allyl bromide, stabilized with 300-1000ppm Propylene oxide

Signal Word

• Danger

Hazard Category

• Acute toxicity Category 3
• ACUTE AQUATIC Acute 1
• Carcinogenicity Category 1B
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 2
• Germ cell mutagenicity Category 1B
• Skin corrosion/irritation Category 1 B

Hazard Statement

• H225-Highly flammable liquid and vapour.
• H301-Toxic if swallowed.
• H314-Causes severe skin burns and eye damage.
• H318-Causes serious eye damage.
• H331-Toxic if inhaled.
• H340-May cause genetic defects.
• H350-May cause cancer.
• H400-Very toxic to aquatic life.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.

Supplemental information

• MIXTURE LIST-Contains : Allyl bromide, Propylene oxide

RUO – Research Use Only