Allylmagnesium chloride, 1.7M solution in THF, AcroSeal™, Thermo Scientific Chemicals

Product Code	Brand	Quantity	Packaging
10372373	Thermo Scientific Acros 209671000	100 mL	AcroSeal™ Glass bottle
10464643	Thermo Scientific Acros 209678000	800 mL	AcroSeal™ Glass Bottle

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Chemical Identifiers

• CAS: 2622-05-1, 592-42-7
• Molecular Weight (g/mol): 100.83
• InChI Key: PLYLAFITHJUEGX-UHFFFAOYSA-M

• Molecular Formula: C3H5ClMg
• MDL Number: MFCD00000473
• SMILES: Cl[Mg]CC=C

Specifications

• Color: Black
• CAS Min %: 15.76, 80.04
• Molecular Formula: C3H5ClMg
• MDL Number: MFCD00000473
• Density: 0.9600g/mL
• Solubility Information: Solubility in water: vigorous reaction.
• SMILES: Cl[Mg]CC=C
• Molecular Weight (g/mol): 100.83
• Formula Weight: 100.83
• Specific Gravity: 0.96
• Physical Form: Liquid

• CAS: 2622-05-1, 592-42-7
• CAS Max %: 19.96, 84.25
• Linear Formula: H₂C=CHCH₂MgCl
• Concentration: 1.5 to 1.9M
• Synonym: tri-o-tolyl phosphite, tri-o-tolylphosphite, tri-o-cresyl phosphite, phosphorous acid tri-o-cresyl ester, tris o-methylphenyl phosphite, tris 2-methylphenyl phosphite, tris 2-tolyl phosphite, tris o-tolyloxy phosphine, phosphorous acid, tri-o-cresyl ester, tri-2-tolylphosphite
• InChI Key: PLYLAFITHJUEGX-UHFFFAOYSA-M
• IUPAC Name: tris(2-methylphenyl) phosphite
• PubChem CID: 92937
• Percent Purity: 1.5 to 1.9M
• Flash Point: −17°C
• Chemical Name or Material: Allylmagnesium chloride, 1.7M Solution in THF

Safety and Handling

GHS H Statement
Causes severe skin burns and eye damage. May cause respiratory irritation. Suspected of causing cancer. Highly flammable liquid and vapor. Reacts violently with water. May form explosive peroxides. In contact with water releases flammable gases which may ignite spontaneously. May cause drowsiness or dizziness.

GHS P Statement
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Handle under inert gas. Protect from moisture. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: rinse mouth. Do NOT induce vomiting. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.

Danger

Product Identifier

• Allylmagnesium chloride, 1.7M solution in THF

Signal Word

• Danger

Hazard Category

• Carcinogenicity Category 2
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 2
• Skin corrosion/irritation Category 1 B
• Specific target organ toxicity Category 3
• Substance which\, in contact with water\, emits flammable gases Category 1

Hazard Statement

• H318-Causes serious eye damage.
• H314-Causes severe skin burns and eye damage.
• H351-Suspected of causing cancer.
• H335-May cause respiratory irritation.
• H336-May cause drowsiness or dizziness.
• H260-In contact with water releases flammable gases which may ignite spontaneously.
• H225-Highly flammable liquid and vapour.
• EUH014-Reacts violently with water.
• EUH019-May form explosive peroxides.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P231+P232-Handle under inert gas. Protect from moisture.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.

RUO – Research Use Only