Allyltri-n-butyltin, 97%, Thermo Scientific Chemicals

Description

Allyltri-n-butyltin acts as an allylation reagent for aldehydes catalyzed by chiral Lewis acids and ytterbium(III) trifluoromethanesulfonate. It is also used to prepare homoallylic alcohols with trichloro-1,3,5-triazene. Further, it plays an important role for tetrakis(triphenylphosphine)palladium(0) catalyzed coupling reaction with iodoquinones and allyl acetates.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Allyltri-n-butyltin acts as an allylation reagent for aldehydes catalyzed by chiral Lewis acids and ytterbium(III) trifluoromethanesulfonate. It is also used to prepare homoallylic alcohols with trichloro-1,3,5-triazene. Further, it plays an important role for tetrakis(triphenylphosphine)palladium(0) catalyzed coupling reaction with iodoquinones and allyl acetates.

Solubility
Immiscible with water.

Notes
Air sensitive. Incompatible with strong oxidizing agents.

Specifications

Chemical Identifiers

• CAS: 24850-33-7
• Molecular Formula: C15H32Sn
• Molecular Weight (g/mol): 331.13
• MDL Number: MFCD00010346
• InChI Key: YLGRTLMDMVAFNI-UHFFFAOYSA-N
• Synonym: allyltributyltin, allyltributylstannane, allyltri-n-butyltin, stannane, tributyl-2-propenyl, tributyl prop-2-en-1-yl stannane, allyl tributyl stannane, unii-aor8od4103, tributyl-2-propenylstannane, tri-n-butyl-2-propenylstannane, allyl tributyltin
• PubChem CID: 90628
• SMILES: CCCC[Sn](CCCC)(CCCC)CC=C

• Density: 1.079
• Boiling Point: 100°C to 102°C (0.5 mmHg)
• Flash Point: 103°C (217°F)
• Refractive Index: 1.486
• Quantity: 5 g
• UN Number: UN2788
• Beilstein: 3588340
• Sensitivity: Air sensitive
• Solubility Information: Immiscible with water.
• IUPAC Name: tributyl(prop-2-enyl)stannane
• Formula Weight: 331.12
• Percent Purity: 97%
• Chemical Name or Material: Allyltri-n-butyltin

RUO – Research Use Only