Allyltri-n-butyltin, 97%, Thermo Scientific Chemicals

Product Code	Brand	Quantity
11368955	Thermo Scientific Alfa Aesar L14087.06	5 g
11378955	Thermo Scientific Alfa Aesar L14087.14	25 g

Description

Allyltri-n-butyltin acts as an allylation reagent for aldehydes catalyzed by chiral Lewis acids and ytterbium(III) trifluoromethanesulfonate. It is also used to prepare homoallylic alcohols with trichloro-1,3,5-triazene. Further, it plays an important role for tetrakis(triphenylphosphine)palladium(0) catalyzed coupling reaction with iodoquinones and allyl acetates.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Allyltri-n-butyltin acts as an allylation reagent for aldehydes catalyzed by chiral Lewis acids and ytterbium(III) trifluoromethanesulfonate. It is also used to prepare homoallylic alcohols with trichloro-1,3,5-triazene. Further, it plays an important role for tetrakis(triphenylphosphine)palladium(0) catalyzed coupling reaction with iodoquinones and allyl acetates.

Solubility
Immiscible with water.

Notes
Air sensitive. Incompatible with strong oxidizing agents.

Chemical Identifiers

• CAS: 24850-33-7
• Molecular Weight (g/mol): 331.13
• InChI Key: YLGRTLMDMVAFNI-UHFFFAOYSA-N
• PubChem CID: 90628

• Molecular Formula: C15H32Sn
• MDL Number: MFCD00010346
• Synonym: allyltributyltin, allyltributylstannane, allyltri-n-butyltin, stannane, tributyl-2-propenyl, tributyl prop-2-en-1-yl stannane, allyl tributyl stannane, unii-aor8od4103, tributyl-2-propenylstannane, tri-n-butyl-2-propenylstannane, allyl tributyltin
• SMILES: CCCC[Sn](CCCC)(CCCC)CC=C

Specifications

• CAS: 24850-33-7
• Boiling Point: 100°C to 102°C (0.5 mmHg)
• Molecular Formula: C15H32Sn
• MDL Number: MFCD00010346
• Beilstein: 3588340
• Synonym: allyltributyltin, allyltributylstannane, allyltri-n-butyltin, stannane, tributyl-2-propenyl, tributyl prop-2-en-1-yl stannane, allyl tributyl stannane, unii-aor8od4103, tributyl-2-propenylstannane, tri-n-butyl-2-propenylstannane, allyl tributyltin
• InChI Key: YLGRTLMDMVAFNI-UHFFFAOYSA-N
• IUPAC Name: tributyl(prop-2-enyl)stannane
• PubChem CID: 90628
• Percent Purity: 97%

• Density: 1.079
• Flash Point: 103°C (217°F)
• Refractive Index: 1.486
• UN Number: UN2788
• Sensitivity: Air sensitive
• Solubility Information: Immiscible with water.
• SMILES: CCCC[Sn](CCCC)(CCCC)CC=C
• Molecular Weight (g/mol): 331.13
• Formula Weight: 331.12
• Chemical Name or Material: Allyltri-n-butyltin

Safety and Handling

GHS H Statement
H301-H372-H312-H315-H319
Toxic if swallowed.
Causes damage to organs through prolonged or repeated exposure.
Harmful in contact with skin.
Causes skin irritation.
Causes serious eye irritation.

P260-P264b-P270-P280-P301+P310-P302+P352-P305+P351+P338-P312-P314-P330-P332+P313-P362-P501c

H301-H312-H315-H319-H372

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missing translation for 'tsca' : No

Recommended Storage : Keep cold; Store under Argon

RUO – Research Use Only