Benzylmagnesium chloride, 1.5M solution in THF, Thermo Scientific Chemicals

Product Code	Brand	Quantity	Packaging
10095093	Thermo Scientific Acros 389551000	100 mL	AcroSeal™ Glass bottle
10463735	Thermo Scientific Acros 389558000	800 mL	AcroSeal™ Glass Bottle

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Chemical Identifiers

• CAS: 6921-34-2, 109-99-9
• Molecular Weight (g/mol): 150.89
• InChI Key: NRAFPLGJPPJUNB-UHFFFAOYSA-M
• PubChem CID: 2733352
• SMILES: Cl[Mg]CC1=CC=CC=C1

• Molecular Formula: C7H7ClMg
• MDL Number: MFCD00000469
• Synonym: benzylmagnesium chloride, magnesium, chloro phenylmethyl, phch2mgcl, benzyl chloro magnesium, benzyl magnesium chloride, chloro phenylmethyl magnesium, benzylmagnesiumchloride, bnmgcl, benzyl-magnesium chloride, chloro phenylmethyl-magnesium
• IUPAC Name: benzyl(chloro)magnesium

Specifications

• Color: Brown to Black
• CAS Min %: 20.51, 75.83
• Molecular Formula: C7H7ClMg
• MDL Number: MFCD00000469
• Density: 1.0300g/mL
• Solubility Information: Solubility in water: reacts.
• SMILES: Cl[Mg]CC1=CC=CC=C1
• Molecular Weight (g/mol): 150.89
• Formula Weight: 150.89
• Specific Gravity: 1.03
• Physical Form: Iridescent Powder or Crystals

• CAS: 6921-34-2, 109-99-9
• CAS Max %: 24.17, 79.49
• Linear Formula: (C₆H₅)CH₂MgCl
• Concentration: 1.40 to 1.65M
• Synonym: benzylmagnesium chloride, magnesium, chloro phenylmethyl, phch2mgcl, benzyl chloro magnesium, benzyl magnesium chloride, chloro phenylmethyl magnesium, benzylmagnesiumchloride, bnmgcl, benzyl-magnesium chloride, chloro phenylmethyl-magnesium
• InChI Key: NRAFPLGJPPJUNB-UHFFFAOYSA-M
• IUPAC Name: benzyl(chloro)magnesium
• PubChem CID: 2733352
• Percent Purity: 19 to 21% (as BMC) (Total base)
• Flash Point: −17°C
• Chemical Name or Material: Benzylmagnesium chloride, 1.5M solution in THF

Safety and Handling

GHS H Statement
Causes severe skin burns and eye damage. May cause respiratory irritation. Highly flammable liquid and vapor. May form explosive peroxides. Reacts violently with water. Suspected of causing cancer. May cause drowsiness or dizziness.

GHS P Statement
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: rinse mouth. Do NOT induce vomiting. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.

Danger

Product Identifier

• Benzylmagnesium chloride, 1-2M solution in THF

Signal Word

• Danger

Hazard Category

• Carcinogenicity Category 2
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 2
• Skin corrosion/irritation Category 1 B
• Specific target organ toxicity Category 3

Hazard Statement

• H225-Highly flammable liquid and vapour.
• H314-Causes severe skin burns and eye damage.
• H318-Causes serious eye damage.
• H335-May cause respiratory irritation.
• H336-May cause drowsiness or dizziness.
• H351-Suspected of causing cancer.
• EUH014-Reacts violently with water.
• EUH019-May form explosive peroxides.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.

Supplemental information

• MIXTURE LIST-Contains : Tetrahydrofuran, Benzylmagnesium chloride

RUO – Research Use Only