Bis[2-(di-tert-butylphosphino)ethyl]amine, 10% w/w soln. in THF, Thermo Scientific Chemicals

Description

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
This compound is involved in the transition metal-catalyzed addition of amines to acrylic acid derivatives.

Solubility
Insoluble in water.

Notes
Air Sensitive. Incompatible with oxidizing agents.

Specifications

Chemical Identifiers

• CAS: 944710-34-3
• Molecular Formula: C20H45NP2
• Molecular Weight (g/mol): 361.54
• MDL Number: MFCD17014018
• InChI Key: MJYKYLNPIGDVEF-UHFFFAOYSA-N
• Synonym: bis 2-di-t-butylphosphino ethyl amine, bis 2-di-tert-butylphosphino ethyl amine, bis 2-di-tert-butylphosphanyl ethyl amine, bis 2-di-tert-butylphosphino ethyl amine w/w soln. in thf, bis 2-di-tert-butylphosphino ethyl amine solution, 10 wt. % in thf
• PubChem CID: 51346231
• IUPAC Name: 2-ditert-butylphosphanyl-N-(2-ditert-butylphosphanylethyl)ethanamine
• SMILES: CC(C)(C)P(CCNCCP(C(C)(C)C)C(C)(C)C)C(C)(C)C

• Density: 0.911
• Odor: Unpleasant
• Linear Formula: ([(CH₃)₃C]₂PCH₂CH₂)₂NH
• Refractive Index: 1.418
• Quantity: 1 g
• UN Number: UN1993
• Sensitivity: Air Sensitive
• Solubility Information: Insoluble in water.
• Formula Weight: 361.53
• Concentration or Composition (by Analyte or Components): 10% w/w soln. in THF
• Chemical Name or Material: Bis[2-(di-tert-butylphosphino)ethyl]amine

Safety and Handling

Product Identifier

• Bis[2-(di-tert-butylphosphino)ethyl]amine, 10% w/w solution in THF

Signal Word

• Danger

Hazard Category

• Acute toxicity Category 4
• Carcinogenicity Category 2
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 2
• Skin corrosion/irritation Category 2
• Specific target organ toxicity Category 3

Hazard Statement

• H225-Highly flammable liquid and vapour.
• H302-Harmful if swallowed.
• H315-Causes skin irritation.
• H318-Causes serious eye damage.
• H335-May cause respiratory irritation.
• H336-May cause drowsiness or dizziness.
• H351-Suspected of causing cancer.
• EUH019-May form explosive peroxides.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.
• P332+P313-If skin irritation occurs: Get medical advice/attention.

Supplemental information

• MIXTURE LIST-Contains : Tetrahydrofuran, Bis[2-(di-tert-butylphosphino)ethyl]amine

RUO – Research Use Only