Cerium(III) chloride heptahydrate, 99%, Thermo Scientific Chemicals

Description

Cerium(III) chloride heptahydrate is used in the preparation of allylsilanes from esters. It is used as a reducing agent in organic synthesis in place of sodium borohydride. In Luche reaction, carvone gives selectively allylic alcohol.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Cerium(III) chloride heptahydrate is used in the preparation of allylsilanes from esters. It is used as a reducing agent in organic synthesis in place of sodium borohydride. In Luche reaction, carvone gives selectively allylic alcohol.

Solubility
Soluble in alcohol and acetone. Slightly soluble in tetrahydrofuran. Insoluble in cold water.

Notes
Air sensitive. Hygroscopic. Incompatible with strong acids and strong oxidizing agents.

Specifications

Chemical Identifiers

• CAS: 18618-55-8
• Molecular Formula: CeCl₃·7H₂O
• MDL Number: MFCD00149634
• Synonym: Cerous chloride heptahydrate

• Quantity: 1000 g
• Merck Index: 14,1997
• Solubility Information: Soluble in alcohol,water,and acetone. Slightly soluble in tetrahydrofuran.
• Formula Weight: 372.60 (246.48 Anhydrous)
• Percent Purity: 99%
• Odor: Odorless
• Sensitivity: Air sensitive; Hygroscopic
• Chemical Name or Material: Cerium(III) chloride heptahydrate

RUO – Research Use Only