Cerium(IV) ammonium nitrate, 98+%, Thermo Scientific Chemicals

Product Code	Brand	Quantity
11445323	Thermo Scientific Alfa Aesar A12882.18	50 g
11455323	Thermo Scientific Alfa Aesar A12882.30	250 g
11435323	Thermo Scientific Alfa Aesar A12882.0B	1000 g

Description

Cerium(IV) ammonium nitrate is widely utilized as an oxidant for many functional groups like alcohols, phenols and ethers as well as C-H bonds. It acts as a deprotection reagent for alcohol in organic synthesis. It is useful in the synthesis of heterocycles like quinoxaline derivatives which is used in dyes, organic semiconductors and DNA cleaving agents. It is an active component of chrome etchant, which is used in the production of photomasks and liquid crystal displays.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Cerium(IV) ammonium nitrate is widely utilized as an oxidant for many functional groups like alcohols, phenols and ethers as well as C-H bonds. It acts as a deprotection reagent for alcohol in organic synthesis. It is useful in the synthesis of heterocycles like quinoxaline derivatives which is used in dyes, organic semiconductors and DNA cleaving agents. It is an active component of chrome etchant, which is used in the production of photomasks and liquid crystal displays.

Solubility
Soluble in water and alcohol.

Notes
Store in cool place. Hygroscopic. Incompatible with strong reducing agents and powdered metals.

Chemical Identifiers

• CAS: 16774-21-3
• Molecular Formula: H₈CeN₈O₁₈
• MDL Number: MFCD00151121
• Synonym: Ammonium cerium(IV) nitrate; CAN

Specifications

• CAS: 16774-21-3
• Linear Formula: (NH₄)₂Ce(NO₃)₆
• UN Number: UN1477
• Synonym: Ammonium cerium(IV) nitrate; CAN
• Formula Weight: 548.23
• Odor: Pungent

• Molecular Formula: H₈CeN₈O₁₈
• MDL Number: MFCD00151121
• Merck Index: 14,1992
• Solubility Information: Soluble in water and alcohol.
• Percent Purity: ≥98%
• Chemical Name or Material: Cerium(IV) ammonium nitrate

Safety and Handling

GHS H Statement
H272-H315-H319-H335
May intensify fire; oxidizer.
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.

P210-P220-P221-P234-P260-P264b-P270-P271-P272-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P333+P313-P363-P370+P378q-P390-P501c

H272-H290-H302-H314-H317-H335

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Recommended Storage : Ambient temperatures

Signal Word

• Danger

Hazard Category

• Acute toxicity Category 4
• LONG-TERM AQUATIC HAZARD Chronic 1
• ACUTE AQUATIC Acute 1
• Serious eye damage/eye irritation Category 1
• Substances and mixtures corrosive to metals Category 1
• Oxidising solid Category 2
• Skin corrosion/irritation Category 1 C
• Skin sensitiser Category 1

Hazard Statement

• H272-May intensify fire; oxidiser.
• H290-May be corrosive to metals.
• H302-Harmful if swallowed.
• H314-Causes severe skin burns and eye damage.
• H317-May cause an allergic skin reaction.
• H318-Causes serious eye damage.
• H400-Very toxic to aquatic life.
• H410-Very toxic to aquatic life with long lasting effects.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P220-Keep/Store away from clothing/combustible materials.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

RUO – Research Use Only