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Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine, 97%, maycontain suspended amine hydrochloride crystals, Thermo Scientific Chemicals
£74.80 - £229.00
Chemical Identifiers
CAS | 142421-57-6 |
---|---|
Molecular Formula | C16H6ClF12P |
Molecular Weight (g/mol) | 492.629 |
MDL Number | MFCD01630852 |
InChI Key | DFZQEHBNAJGDCT-UHFFFAOYSA-N |
Synonym | bis 3,5-di trifluoromethyl phenyl chlorophosphine, phosphinous chloride, bis 3,5-bis trifluoromethyl phenyl, acmc-20alnu, bis 3,5-bis trifluoromethyl phenyl chlorophosphine, bis 3,5-bis trifluoromethyl phenyl-chlorophosphane, bis 3,5-bis trifluoromethyl phenyl-chlorophosphine, bis 3,5-bis trifluoromethyl phenyl chloro phosphane, p,p-bis 3,5-bis trifluoromethyl phenyl phosphinous chloride, phosphinous chloride,p,p-bis 3,5-bis trifluoromethyl phenyl |
PubChem CID | 5104965 |
IUPAC Name | bis[3,5-bis(trifluoromethyl)phenyl]-chlorophosphane |
SMILES | C1=C(C=C(C=C1C(F)(F)F)P(C2=CC(=CC(=C2)C(F)(F)F)C(F)(F)F)Cl)C(F)(F)F |
Description
Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine is used as a reactant for the synthesis of chiral phosphine-aminophosphine ligands for rhodium-catalyzed asymmetric hydrogenation, ligands for palladium-catalyzed stereoselective allylation reactions, enantioselective hydrogenations, Josiphos analog as catalyst for asymmetric hydrogenation, ligands used in asymmetric hydrovinylation reactions.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsChlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine is used as a reactant for the synthesis of chiral phosphine-aminophosphine ligands for rhodium-catalyzed asymmetric hydrogenation, ligands for palladium-catalyzed stereoselective allylation reactions, enantioselective hydrogenations, Josiphos analog as catalyst for asymmetric hydrogenation, ligands used in asymmetric hydrovinylation reactions.
Solubility
Reacts with water.
Notes
Air & moisture sensitive. Store away from oxidizing agents, bases, air, water/ moisture.
Chemical Identifiers
142421-57-6 | |
492.629 | |
DFZQEHBNAJGDCT-UHFFFAOYSA-N | |
5104965 | |
C1=C(C=C(C=C1C(F)(F)F)P(C2=CC(=CC(=C2)C(F)(F)F)C(F)(F)F)Cl)C(F)(F)F |
C16H6ClF12P | |
MFCD01630852 | |
bis 3,5-di trifluoromethyl phenyl chlorophosphine, phosphinous chloride, bis 3,5-bis trifluoromethyl phenyl, acmc-20alnu, bis 3,5-bis trifluoromethyl phenyl chlorophosphine, bis 3,5-bis trifluoromethyl phenyl-chlorophosphane, bis 3,5-bis trifluoromethyl phenyl-chlorophosphine, bis 3,5-bis trifluoromethyl phenyl chloro phosphane, p,p-bis 3,5-bis trifluoromethyl phenyl phosphinous chloride, phosphinous chloride,p,p-bis 3,5-bis trifluoromethyl phenyl | |
bis[3,5-bis(trifluoromethyl)phenyl]-chlorophosphane |
Specifications
142421-57-6 | |
MFCD01630852 | |
Air and moisture sensitive; May form a precipitate | |
Reacts with water. | |
C1=C(C=C(C=C1C(F)(F)F)P(C2=CC(=CC(=C2)C(F)(F)F)C(F)(F)F)Cl)C(F)(F)F | |
492.629 | |
492.63 | |
may contain suspended dimethylamine hydrochloride crystals |
C16H6ClF12P | |
UN3265 | |
bis 3,5-di trifluoromethyl phenyl chlorophosphine, phosphinous chloride, bis 3,5-bis trifluoromethyl phenyl, acmc-20alnu, bis 3,5-bis trifluoromethyl phenyl chlorophosphine, bis 3,5-bis trifluoromethyl phenyl-chlorophosphane, bis 3,5-bis trifluoromethyl phenyl-chlorophosphine, bis 3,5-bis trifluoromethyl phenyl chloro phosphane, p,p-bis 3,5-bis trifluoromethyl phenyl phosphinous chloride, phosphinous chloride,p,p-bis 3,5-bis trifluoromethyl phenyl | |
DFZQEHBNAJGDCT-UHFFFAOYSA-N | |
bis[3,5-bis(trifluoromethyl)phenyl]-chlorophosphane | |
5104965 | |
≥98% | |
Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine |
Safety and Handling
GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.
P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c
H314-H335
missing translation for 'dotInformation' : Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
missing translation for 'einecsNumber' : 000-000-0
missing translation for 'tsca' : No
Recommended Storage : Ambient temperatures; Store under Nitrogen
RUO – Research Use Only