missing translation for 'onlineSavingsMsg'
Learn More

Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine, 97%, maycontain suspended amine hydrochloride crystals, Thermo Scientific Chemicals

£74.80 - £229.00

Chemical Identifiers

CAS 142421-57-6
Molecular Formula C16H6ClF12P
Molecular Weight (g/mol) 492.629
MDL Number MFCD01630852
InChI Key DFZQEHBNAJGDCT-UHFFFAOYSA-N
Synonym bis 3,5-di trifluoromethyl phenyl chlorophosphine, phosphinous chloride, bis 3,5-bis trifluoromethyl phenyl, acmc-20alnu, bis 3,5-bis trifluoromethyl phenyl chlorophosphine, bis 3,5-bis trifluoromethyl phenyl-chlorophosphane, bis 3,5-bis trifluoromethyl phenyl-chlorophosphine, bis 3,5-bis trifluoromethyl phenyl chloro phosphane, p,p-bis 3,5-bis trifluoromethyl phenyl phosphinous chloride, phosphinous chloride,p,p-bis 3,5-bis trifluoromethyl phenyl
PubChem CID 5104965
IUPAC Name bis[3,5-bis(trifluoromethyl)phenyl]-chlorophosphane
SMILES C1=C(C=C(C=C1C(F)(F)F)P(C2=CC(=CC(=C2)C(F)(F)F)C(F)(F)F)Cl)C(F)(F)F
View More Specs

Products 2
Product Code Brand Quantity Price Quantity & Availability  
Product Code Brand Quantity Price Quantity & Availability  
11495620
View Documents Promotion Details
Thermo Scientific Alfa Aesar
H25883.03
1 g This item is currently unavailable or has been discontinued.
View the product page for possible alternatives.
N/A
11405630
View Documents Promotion Details
Thermo Scientific Alfa Aesar
H25883.06
5 g This item is currently unavailable or has been discontinued.
View the product page for possible alternatives.
N/A
Description

Description

Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine is used as a reactant for the synthesis of chiral phosphine-aminophosphine ligands for rhodium-catalyzed asymmetric hydrogenation, ligands for palladium-catalyzed stereoselective allylation reactions, enantioselective hydrogenations, Josiphos analog as catalyst for asymmetric hydrogenation, ligands used in asymmetric hydrovinylation reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine is used as a reactant for the synthesis of chiral phosphine-aminophosphine ligands for rhodium-catalyzed asymmetric hydrogenation, ligands for palladium-catalyzed stereoselective allylation reactions, enantioselective hydrogenations, Josiphos analog as catalyst for asymmetric hydrogenation, ligands used in asymmetric hydrovinylation reactions.

Solubility
Reacts with water.

Notes
Air & moisture sensitive. Store away from oxidizing agents, bases, air, water/ moisture.
Specifications

Chemical Identifiers

142421-57-6
492.629
DFZQEHBNAJGDCT-UHFFFAOYSA-N
5104965
C1=C(C=C(C=C1C(F)(F)F)P(C2=CC(=CC(=C2)C(F)(F)F)C(F)(F)F)Cl)C(F)(F)F
C16H6ClF12P
MFCD01630852
bis 3,5-di trifluoromethyl phenyl chlorophosphine, phosphinous chloride, bis 3,5-bis trifluoromethyl phenyl, acmc-20alnu, bis 3,5-bis trifluoromethyl phenyl chlorophosphine, bis 3,5-bis trifluoromethyl phenyl-chlorophosphane, bis 3,5-bis trifluoromethyl phenyl-chlorophosphine, bis 3,5-bis trifluoromethyl phenyl chloro phosphane, p,p-bis 3,5-bis trifluoromethyl phenyl phosphinous chloride, phosphinous chloride,p,p-bis 3,5-bis trifluoromethyl phenyl
bis[3,5-bis(trifluoromethyl)phenyl]-chlorophosphane

Specifications

142421-57-6
MFCD01630852
Air and moisture sensitive; May form a precipitate
Reacts with water.
C1=C(C=C(C=C1C(F)(F)F)P(C2=CC(=CC(=C2)C(F)(F)F)C(F)(F)F)Cl)C(F)(F)F
492.629
492.63
may contain suspended dimethylamine hydrochloride crystals
C16H6ClF12P
UN3265
bis 3,5-di trifluoromethyl phenyl chlorophosphine, phosphinous chloride, bis 3,5-bis trifluoromethyl phenyl, acmc-20alnu, bis 3,5-bis trifluoromethyl phenyl chlorophosphine, bis 3,5-bis trifluoromethyl phenyl-chlorophosphane, bis 3,5-bis trifluoromethyl phenyl-chlorophosphine, bis 3,5-bis trifluoromethyl phenyl chloro phosphane, p,p-bis 3,5-bis trifluoromethyl phenyl phosphinous chloride, phosphinous chloride,p,p-bis 3,5-bis trifluoromethyl phenyl
DFZQEHBNAJGDCT-UHFFFAOYSA-N
bis[3,5-bis(trifluoromethyl)phenyl]-chlorophosphane
5104965
≥98%
Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine
Videos
Safety and Handling

Safety and Handling

GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.

P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

H314-H335

missing translation for 'dotInformation' : Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.

missing translation for 'einecsNumber' : 000-000-0

missing translation for 'tsca' : No

Recommended Storage : Ambient temperatures; Store under Nitrogen

SDS
Documents

Documents

Product Certifications

RUO – Research Use Only