Chlorodimethylphenylsilane, 97+%, Thermo Scientific Chemicals

Product Code	Brand	Quantity
11457537	Thermo Scientific Alfa Aesar A15638.06	5 g
11467537	Thermo Scientific Alfa Aesar A15638.14	25 g
11477537	Thermo Scientific Alfa Aesar A15638.22	100 g

Description

Chlorodimethylphenylsilane is used in the synthesis of enantioenriched allenylsilanes through an ortho-ester Claisen rearrangement of chiral and silylpropargylic alcohols.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Chlorodimethylphenylsilane is used in the synthesis of enantioenriched allenylsilanes through an ortho-ester Claisen rearrangement of chiral and silylpropargylic alcohols.

Solubility
Miscible with tetrahydrofuran, ether and hexane.

Notes
Incompatible with strong oxidizing agents, acids, bases, and moisture.

Chemical Identifiers

• CAS: 768-33-2
• Molecular Weight (g/mol): 170.71
• InChI Key: KWYZNESIGBQHJK-UHFFFAOYSA-N
• PubChem CID: 13029
• SMILES: C[Si](C)(Cl)C1=CC=CC=C1

• Molecular Formula: C8H11ClSi
• MDL Number: MFCD00000499
• Synonym: chlorodimethylphenylsilane, chlorodimethyl phenyl silane, phenyldimethylchlorosilane, silane, chlorodimethylphenyl, dimethylphenylchlorosilane, chloro dimethyl phenylsilane, phenyl dimethylchlorosilane, chloro-dimethyl-phenyl-silane, benzene, chlorodimethylsilyl, pubchem10814
• IUPAC Name: chloro-dimethyl-phenylsilane

Specifications

• Boiling Point: 192°C to 193°C
• Molecular Formula: C8H11ClSi
• UN Number: UN2987
• Flash Point: 72°C (161°F)
• Solubility Information: Miscible with tetrahydrofuran,ether and hexane.
• SMILES: C[Si](C)(Cl)C1=CC=CC=C1
• Molecular Weight (g/mol): 170.71
• Formula Weight: 170.72
• Refractive Index: 1.509
• Density: 1.032

• CAS: 768-33-2
• MDL Number: MFCD00000499
• Beilstein: 606292
• Synonym: chlorodimethylphenylsilane, chlorodimethyl phenyl silane, phenyldimethylchlorosilane, silane, chlorodimethylphenyl, dimethylphenylchlorosilane, chloro dimethyl phenylsilane, phenyl dimethylchlorosilane, chloro-dimethyl-phenyl-silane, benzene, chlorodimethylsilyl, pubchem10814
• InChI Key: KWYZNESIGBQHJK-UHFFFAOYSA-N
• IUPAC Name: chloro-dimethyl-phenylsilane
• PubChem CID: 13029
• Percent Purity: ≥97%
• Sensitivity: Moisture sensitive
• Chemical Name or Material: Chlorodimethylphenylsilane

Safety and Handling

GHS H Statement
H314-H318-H227
Causes severe skin burns and eye damage.
Causes serious eye damage.
Combustible liquid.

P210-P260-P264b-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P370+P378q-P501c

H227-H314

missing translation for 'dotInformation' : Transport Hazard Class: 8; Packing Group: II; Proper Shipping Name: CHLOROSILANES, CORROSIVE, N.O.S.

missing translation for 'einecsNumber' : 212-193-0

missing translation for 'tsca' : Yes

Recommended Storage : Ambient temperatures; Store under Nitrogen

RUO – Research Use Only