Chlorotris(triphenylphosphine)rhodium(I), 97%, Thermo Scientific Chemicals

Product Code. 11305978

Brand: Thermo Scientific Alfa Aesar 010468.03

Description

Chlorotris(triphenylphosphine)rhodium(I) is used as a homogeneous hydrogenation catalyst. It is used in the selective hydrogenation of alkenes and alkynes.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Specifications

Chemical Identifiers

• CAS: 14694-95-2
• Molecular Formula: C54H45ClP3Rh
• Molecular Weight (g/mol): 925.23
• MDL Number: MFCD00010016
• InChI Key: IXAYKDDZKIZSPV-UHFFFAOYSA-M
• Synonym: chlorotris triphenylphosphine rhodium i, chlorotris triphenylphosphine rhodium, tris triphenylphosphine rhodium i chloride, tris triphenylphosphine chlororhodium, wilkinson's catalyst, unii-0fv534bkev, tris triphenylphosphine rhodium chloride, 0fv534bkev, rhodium; triphenylphosphane; chloride
• PubChem CID: 84599
• IUPAC Name: rhodium;triphenylphosphane;chloride
• SMILES: [Cl-].[Rh+].C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1.C1=CC=C(C=C1)P(C1=CC=CC=C1)C1=CC=CC=C1

• Melting Point: ∼250°C (decomposition)
• Color: Red
• Odor: Odorless
• Linear Formula: RhCl[(C₆H₅)₃P]₃
• Quantity: 1 g
• Merck Index: 14,10047
• Solubility Information: Soluble in most solvents (e;g; benzene,ethanol,chloroform,dichloromethane) but with phosphine dissociation; Reacts with O₂ in solution
• Formula Weight: 925.23
• Percent Purity: 97%
• Physical Form: Micro Crystals
• Chemical Name or Material: Chlorotris(triphenylphosphine)rhodium(I)

Safety and Handling

SDS

RUO – Research Use Only