Diisobutylaluminium hydride, 1M solution in hexane, AcroSeal™, Thermo Scientific Chemicals

Product Code	Brand	Quantity	Packaging
10309812	Thermo Scientific Acros 183791000	100 mL	AcroSeal™ Glass bottle
10368003	Thermo Scientific Acros 183798000	800 mL	AcroSeal™ Glass Bottle

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Lewis acid, Reduction reagent

Specifications

• Chemical Name or Material: Diisobutylaluminium hydride
• CAS: 1191-15-7, 110-54-3
• Density: 0.7010g/mL
• Molecular Formula: C₈H₁₉Al
• MDL Number: MFCD00008928
• Fieser: 01,260; 02,140; 03,101; 04,158; 05,224; 06,198; 07,111; 08,173; 09,171; 10,149; 11,185; 12,191; 13,115; 14,138; 15,137; 16,27; 17,123
• Specific Gravity: 0.701
• Solubility Information: Solubility in water: reacts
• Formula Weight: 142.22

• Name Note: 1M Solution in Hexane
• Melting Point: -70.0°C
• Flash Point: −23°C
• Linear Formula: [(CH₃)₂CHCH₂]₂AlH
• Beilstein: 04, IV, 4400
• Merck Index: 15, 3212
• Synonym: DIBAL-H
• Molecular Weight (g/mol): 142.22
• Physical Form: Solution

Safety and Handling

GHS H Statement
May be fatal if swallowed and enters airways.
Toxic to aquatic life with long lasting effects.
Causes severe skin burns and eye damage.
May cause drowsiness or dizziness.
May cause damage to organs through p

GHS P Statement
IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses,if present and easy to do.
Continue rinsing.
Keep away from heat/sparks/open flames/hot surfaces.
- No smoking.
Wear protective g

GHS Signal Word: Danger

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Product Identifier

• Diisobutylaluminium hydride, 1M solution in hexane

Signal Word

• Danger

Hazard Category

• Flammable liquid Category 2
• Substance which\, in contact with water\, emits flammable gases Category 1
• Pyrophoric liquid Category 1
• Aspiration toxicity Category 1
• Skin corrosion/irritation Category 1 A
• Reproductive toxicity Category 2
• Specific target organ toxicity Category 3
• Specific target organ toxicity after repeated exposure Category 2
• LONG-TERM AQUATIC HAZARD Chronic 2

Hazard Statement

• H225-Highly flammable liquid and vapour.
• H250-Catches fire spontaneously if exposed to air.
• H260-In contact with water releases flammable gases which may ignite spontaneously.
• H304-May be fatal if swallowed and enters airways.
• H411-Toxic to aquatic life with long lasting effects.
• H314-Causes severe skin burns and eye damage.
• H336-May cause drowsiness or dizziness.
• H373-May cause damage to organs.
• H361f-Suspected of damaging fertility.
• EUH014-Reacts violently with water.

Precautionary Statement

• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P231+P232-Handle under inert gas. Protect from moisture.
• P302+P334-IF ON SKIN: Immerse in cool water/wrap in wet bandages.
• P335+P334-Brush off loose particles from skin Immerse in cool water/wrap in wet bandages.
• P310-Immediately call a POISON CENTER/doctor/.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P273-Avoid release to the environment.
• P402+P404-Store in a dry place. Store in a closed container.
• P222-Do not allow contact with air.

Supplemental information

• MIXTURE LIST-Contains : Hexane, Diisobutylaluminum hydride

RUO – Research Use Only