Ethylmagnesium bromide, ca. 3.2M solution in 2-MeTHF; AcroSeal™, Thermo Scientific Chemicals

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Specifications

Chemical Identifiers

• CAS: 925-90-6, 96-47-9
• Molecular Formula: C2H5BrMg
• Molecular Weight (g/mol): 133.27
• MDL Number: MFCD00000043
• InChI Key: TWTWFMUQSOFTRN-UHFFFAOYSA-M
• Synonym: ethylmagnesium bromide, ethyl magnesium bromide, magnesium, bromoethyl, ethylmagnesiumbromide, bromoethylmagnesium, ethylmagnesium bromide solution, 1.0 m in thf, ethylmagnesium bromide solution, 3.0 m in diethyl ether, etmgbr, ethylmagnesiumbromid, ethylmagnesium bromid, grignard reagent
• PubChem CID: 101914
• IUPAC Name: bromo(ethyl)magnesium
• SMILES: CC[Mg]Br

• Color: Brown
• Linear Formula: CH₃CH₂MgBr
• Concentration: 39 to 41%
• Fieser: 02,205
• Density: 1.1400g/mL
• Solubility Information: Solubility in water: reacts.
• Formula Weight: 133.27
• Packaging: AcroSeal™ Glass bottle
• Specific Gravity: 1.14
• Quantity: 100 mL
• Flash Point: −11°C
• Physical Form: Liquid
• Chemical Name or Material: Ethylmagnesium bromide, 3.2M solution in 2-Methyltetrahydrofuran

Safety and Handling

Product Identifier

• Ethylmagnesium bromide, ca. 3.2M solution in 2-Methyltetrahydrofuran

Signal Word

• Danger

Hazard Category

• Acute toxicity Category 4
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 2
• Skin corrosion/irritation Category 1 B
• Substance which\, in contact with water\, emits flammable gases Category 1

Hazard Statement

• H318-Causes serious eye damage.
• H314-Causes severe skin burns and eye damage.
• H302-Harmful if swallowed.
• H260-In contact with water releases flammable gases which may ignite spontaneously.
• H225-Highly flammable liquid and vapour.
• EUH014-Reacts violently with water.
• EUH019-May form explosive peroxides.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.

RUO – Research Use Only