Isopropenylmagnesium bromide, 0.5M solution in THF, AcroSeal™, Thermo Scientific Chemicals

Product Code	Brand	Quantity	Packaging
10112774	Thermo Scientific Acros 427751000	100 mL	AcroSeal™ Glass bottle
10684175	Thermo Scientific Acros 427758000	800 mL	AcroSeal™ Glass Bottle

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Chemical Identifiers

• CAS: 13291-18-4, 109-99-9
• Molecular Weight (g/mol): 145.28
• InChI Key: LFTYALBVGVNGLI-UHFFFAOYSA-M
• PubChem CID: 4187787
• SMILES: CC(=C)[Mg]Br

• Molecular Formula: C3H5BrMg
• MDL Number: MFCD00192240
• Synonym: isopropenylmagnesium bromide, isopropenylmagnesium bromide solution, isopropenyl magnesium bromide, bromo prop-1-en-2-yl magnesium, magnesium, bromo 1-methylethenyl, bromo isopropenyl magnesium, 1-methylethenylmagnesium bromide, 2-propen-2-ylmagnesium bromide, prop-1-en-2-ylmagnesium bromide, lftyalbvgvngli-uhfffaoysa-m, grignard reagent
• IUPAC Name: magnesium;prop-1-ene;bromide

Specifications

• CAS: 13291-18-4, 109-99-9
• Density: 0.9270g/mL
• Flash Point: 2°C
• Linear Formula: CH₂=C(CH₃)MgBr
• Specific Gravity: 0.927
• InChI Key: LFTYALBVGVNGLI-UHFFFAOYSA-M
• IUPAC Name: magnesium;prop-1-ene;bromide
• PubChem CID: 4187787
• Physical Form: Crystalline Powder

• Color: Orange to White
• Boiling Point: 67.0°C
• Molecular Formula: C3H5BrMg
• MDL Number: MFCD00192240
• Synonym: isopropenylmagnesium bromide, isopropenylmagnesium bromide solution, isopropenyl magnesium bromide, bromo prop-1-en-2-yl magnesium, magnesium, bromo 1-methylethenyl, bromo isopropenyl magnesium, 1-methylethenylmagnesium bromide, 2-propen-2-ylmagnesium bromide, prop-1-en-2-ylmagnesium bromide, lftyalbvgvngli-uhfffaoysa-m, grignard reagent
• SMILES: CC(=C)[Mg]Br
• Molecular Weight (g/mol): 145.28
• Formula Weight: 145.28
• Chemical Name or Material: Isopropenylmagnesium bromide, 0.5M Solution in THF

Safety and Handling

GHS H Statement
Causes severe skin burns and eye damage.
May cause respiratory irritation.
Highly flammable liquid and vapor.
In contact with water releases flammable gases which may ignite spontaneously.
May form explosive

GHS P Statement
Keep away from heat/sparks/open flames/hot surfaces.
- No smoking.
IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water/shower.
Handle under inert gas.
Protect from moisture

GHS Signal Word: Danger

Product Identifier

• Isopropenylmagnesium bromide, 05M solution in THF

Signal Word

• Danger

Hazard Category

• Acute toxicity Category 4
• Carcinogenicity Category 2
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 2
• Skin corrosion/irritation Category 1 A
• Specific target organ toxicity Category 3
• Substance which\, in contact with water\, emits flammable gases Category 1

Hazard Statement

• H318-Causes serious eye damage.
• H314-Causes severe skin burns and eye damage.
• H351-Suspected of causing cancer.
• H335-May cause respiratory irritation.
• H336-May cause drowsiness or dizziness.
• H302-Harmful if swallowed.
• H260-In contact with water releases flammable gases which may ignite spontaneously.
• H225-Highly flammable liquid and vapour.
• EUH014-Reacts violently with water.
• EUH019-May form explosive peroxides.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P231+P232-Handle under inert gas. Protect from moisture.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.

RUO – Research Use Only