Isopropylmagnesium chloride - LiCl complex, 1M in MeTHF, Thermo Scientific Chemicals

Description

Isopropylmagnesium chloride is used in the regioselective functionalization of trisubstituted pyridines, electrophilic amination for preparation of amines and functionalization of cyclopentene derivatives. It is involved in the preparation of 2,3-functionalized furans, benzofurans, and thiophenes. Further, it is used in benzylic Grignards via sulfur-magnesium exchange.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Isopropylmagnesium chloride is used in the regioselective functionalization of trisubstituted pyridines, electrophilic amination for preparation of amines and functionalization of cyclopentene derivatives. It is involved in the preparation of 2,3-functionalized furans, benzofurans, and thiophenes. Further, it is used in benzylic Grignards via sulfur-magnesium exchange.

Solubility
Miscible with ethers and amines.

Notes
Air and moisture sensitive. Incompatible with oxidizing agents and water.

Specifications

Chemical Identifiers

• CAS: 807329-97-1
• Molecular Formula: C3H7Cl2LiMg
• Molecular Weight (g/mol): 145.23
• MDL Number: MFCD07784514
• InChI Key: CWTUREABAILGIK-UHFFFAOYSA-L
• Synonym: turbo grignard, iprmgcl licl, i-prmgcl licl, i-prmgcl.licl, isopropylmagnesiumchloride licl, isopropylmagnesium chloride licl, isopropyl magnesium chloride licl, cwtureabailgik-uhfffaoysa-l, isopropylmagnesium lithium chloride, isopropyl magnesium chloride li-cl
• IUPAC Name: lithium(1+) chloro(propan-2-yl)magnesium chloride
• SMILES: [Li+].[Cl-].CC(C)[Mg]Cl

• Density: 0.951
• Flash Point: −17°C (1.4°F)
• Linear Formula: (CH₃)₂CHMgCl·LiCl
• Quantity: 100 mL
• UN Number: UN3399
• Sensitivity: Air and moisture sensitive
• Solubility Information: Miscible with ethers and amines.
• Formula Weight: 145.24
• Concentration or Composition (by Analyte or Components): 1M in MeTHF
• Chemical Name or Material: Isopropylmagnesium chloride - LiCl complex

RUO – Research Use Only