Isopropylzinc bromide, 0.5M in THF, packaged under Argon in resealable ChemSeal™ bottles, Thermo Scientific Chemicals

Description

 

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Isopropylzinc bromide is employed in croos-coupling reactions.

Solubility
Reacts with water.

Notes
Handle under dry protective gas. Air sensitive. Store away from strong bases and oxidizing agents,

Specifications

• CAS: 77047-87-1
• Density: 0.963
• Molecular Formula: C3H7BrZn
• Linear Formula: (CH₃)₂CHZnBr
• MDL Number: MFCD06200639
• Quantity: 50 mL
• UN Number: UN3399
• Sensitivity: Air sensitive
• Synonym: 2-propylzinc bromide solution 0.5m in t, bromo isopropyl zinc, 2-propylzinc bromide, 0.50 m in thf, 2-propylzinc bromide 0.5 m in tetrahydrofuran, 2-propylzinc bromide solution, 0.5 m in thf, isopropylzinc bromide, 0.5m in thf, packaged under argon in resealable chemseal bottles
• Solubility Information: Reacts with water.
• InChI Key: NTUATXZETUXBSR-UHFFFAOYSA-M
• SMILES: [Zn+]Br.C[CH-]C
• IUPAC Name: bromozincylium; propan-2-ide
• Molecular Weight (g/mol): 188.37
• PubChem CID: 12910424
• Formula Weight: 188.37
• Chemical Name or Material: Isopropylzinc bromide, Packaged under Argon in resealable ChemSeal™ bottles

Safety and Handling

Product Identifier

• Isopropylzinc bromide, 0.5M in THF

Signal Word

• Danger

Hazard Category

• Acute toxicity Category 4
• Carcinogenicity Category 2
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 2
• Skin corrosion/irritation Category 1 B
• Specific target organ toxicity Category 3
• Substance which\, in contact with water\, emits flammable gases Category 1

Hazard Statement

• H225-Highly flammable liquid and vapour.
• H260-In contact with water releases flammable gases which may ignite spontaneously.
• H302-Harmful if swallowed.
• H314-Causes severe skin burns and eye damage.
• H318-Causes serious eye damage.
• H335-May cause respiratory irritation.
• H336-May cause drowsiness or dizziness.
• H351-Suspected of causing cancer.
• EUH019-May form explosive peroxides.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P231-Handle under inert gas.
• P232-Protect from moisture.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.
• P335+P334-Brush off loose particles from skin Immerse in cool water/wrap in wet bandages.

Supplemental information

• MIXTURE LIST-Contains : Tetrahydrofuran, Isopropylzinc bromide

RUO – Research Use Only