Lithium aluminum hydride, 15% solution in toluene/THF, Thermo Scientific™

Product Code	Brand	Quantity	Packaging
10279043	Thermo Scientific Acros 385578000	800 mL	AcroSeal™ Glass Bottle

Description

This Thermo Scientific brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific.

Reduction reagent

Chemical Identifiers

• CAS: 16853-85-3, 108-88-3, 109-99-9
• Molecular Weight (g/mol): 37.95
• InChI Key: OCZDCIYGECBNKL-UHFFFAOYSA-N
• PubChem CID: 21226445
• SMILES: [Li+].[AlH4-]

• Molecular Formula: AlH4Li
• MDL Number: MFCD00011075
• Synonym: lithium aluminum hydride, aluminum lithium hydride, lithiumaluminiumhydride, aluminum iii lithium hydride, lithium alanate, lithium aluminum tetrahydride, lithiumaluminiumhydrid, litiumaluminum hydride, lithim aluminum hydride
• IUPAC Name: lithium(1+) alumanuide

Specifications

• Color: Turbid solution
• Molecular Formula: AlH4Li
• MDL Number: MFCD00011075
• Density: 0.8900g/mL
• InChI Key: OCZDCIYGECBNKL-UHFFFAOYSA-N
• IUPAC Name: lithium(1+) alumanuide
• PubChem CID: 21226445
• Specific Gravity: 0.89
• Chemical Name or Material: Lithium Aluminum hydride, 15% solution in toluene/THF

• CAS: 16853-85-3, 108-88-3, 109-99-9
• Linear Formula: LiAlH₄
• Concentration: ca 15%, exact strength on the certificate of analysis
• Synonym: lithium aluminum hydride, aluminum lithium hydride, lithiumaluminiumhydride, aluminum iii lithium hydride, lithium alanate, lithium aluminum tetrahydride, lithiumaluminiumhydrid, litiumaluminum hydride, lithim aluminum hydride
• SMILES: [Li+].[AlH4-]
• Molecular Weight (g/mol): 37.95
• Formula Weight: 37.95
• Flash Point: −20°C

Safety and Handling

GHS H Statement
Causes severe skin burns and eye damage. Suspected of damaging the unborn child. May be fatal if swallowed and enters airways. May cause damage to organs through prolonged or repeated exposure. May cause drowsiness or dizziness. May cause respiratory irritation. Highly flammable liquid and vapor. In contact with water releases flammable gases which may ignite spontaneously. May form explosive peroxides. Suspected of causing cancer.

GHS P Statement
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Handle under inert gas. Protect from moisture. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: rinse mouth. Do NOT induce vomiting. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.

Danger

Product Identifier

• Lithium aluminium hydride, 15% solution in toluene/THF

Signal Word

• Danger

Hazard Category

• Aspiration toxicity Category 1
• Carcinogenicity Category 2
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 2
• Reproductive toxicity Category 2
• Skin corrosion/irritation Category 1 A
• Specific target organ toxicity after repeated exposure Category 2
• Specific target organ toxicity Category 3
• Substance which\, in contact with water\, emits flammable gases Category 1

Hazard Statement

• H304-May be fatal if swallowed and enters airways.
• H318-Causes serious eye damage.
• H314-Causes severe skin burns and eye damage.
• H351-Suspected of causing cancer.
• H361d-Suspected of damaging the unborn child.
• H373-May cause damage to organs.
• H335-May cause respiratory irritation.
• H336-May cause drowsiness or dizziness.
• H260-In contact with water releases flammable gases which may ignite spontaneously.
• H225-Highly flammable liquid and vapour.
• EUH019-May form explosive peroxides.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P231+P232-Handle under inert gas. Protect from moisture.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.