Lithium diisopropylamide, 2M sol. in THF/n-heptane/ethylbenzene, AcroSeal™, Thermo Scientific Chemicals

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Specifications

Chemical Identifiers

• CAS: 4111-54-0, 142-82-5, 109-99-9, 100-41-4, 108-18-9
• Molecular Formula: C6H14LiN
• Molecular Weight (g/mol): 107.125
• MDL Number: MFCD00064449
• InChI Key: ZCSHNCUQKCANBX-UHFFFAOYSA-N
• Synonym: lithium diisopropylamide, unii-ol028kiw1i, lithium di-isopropylamide, lithium diisopropyl amide, 2-propanamine, n-1-methylethyl-, lithium salt, ol028kiw1i, lithium di propan-2-yl azanide, 2-propanamine, n-1-methylethyl-, lithium salt 1:1, lithium n,n-diisopropylamide, ipr2nli
• PubChem CID: 2724682
• IUPAC Name: lithium;di(propan-2-yl)azanide
• SMILES: [Li+].CC(C)[N-]C(C)C

• Color: Brown-Red or Orange to Yellow
• Boiling Point: 60.0°C to 136.0°C
• Composition: Solvent: THF 59%, n-Heptane: 28%, Ethylbenzene: 13%
• Concentration: Lithium diisopropylamide: 26.0% (2.0M)
• Fieser: 02,49; 03,184; 04,298; 05,400; 06,334; 07,204; 08,292; 09,280; 10,241; 11,296; 12,277; 14,193; 15,188; 16,15; 17,165
• Density: 0.8100g/mL
• Merck Index: 15, 3215
• Solubility Information: Solubility in water: decomposes. Other solubilities: soluble in thf, n-heptane, ethylbenzene, miscible with liquid aliphatic and aromatic, hydrocarbons, ethers and tertiary amines
• Formula Weight: 107.12
• Percent Purity: 24.6 to 30.0% (Lithium diisopropylamide)
• Packaging: AcroSeal™ Glass bottle
• Specific Gravity: 0.81
• Quantity: 100 mL
• Flash Point: 2°C
• Physical Form: Solution
• Chemical Name or Material: Lithium diisopropylamide, 2M Solution in THF/n-Heptane

Safety and Handling

Product Identifier

• Lithium diisopropylamide, 2M solution in THF/n-heptane/ethylbenzene

Signal Word

• Danger

Hazard Category

• Acute toxicity Category 4
• LONG-TERM AQUATIC HAZARD Chronic 2
• Aspiration toxicity Category 1
• Carcinogenicity Category 2
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 2
• Skin corrosion/irritation Category 1 B
• Specific target organ toxicity after repeated exposure Category 2
• Specific target organ toxicity Category 3

Hazard Statement

• H304-May be fatal if swallowed and enters airways.
• H318-Causes serious eye damage.
• H314-Causes severe skin burns and eye damage.
• H351-Suspected of causing cancer.
• H373-May cause damage to organs.
• H411-Toxic to aquatic life with long lasting effects.
• H335-May cause respiratory irritation.
• H336-May cause drowsiness or dizziness.
• H302-Harmful if swallowed.
• H225-Highly flammable liquid and vapour.
• EUH014-Reacts violently with water.
• EUH019-May form explosive peroxides.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.

RUO – Research Use Only