Lithium perchlorate, anhydrous, ACS, 95.0% min, Thermo Scientific Chemicals

Description

As an oxidizing agent

Lithium perchlorate is used as an oxygen source for chemical oxygen generators, as it liberates oxygen at high temperatures. Excellent solubility of lithium perchlorate permits its use in Diels-Alder reactions. It is also employed in lithium-ion batteries as an electrolyte, and act as chaotropic agent to denature proteins. It is used in the Baylis-Hillman reaction as a catalyst in the coupling of alpha, beta-unsaturated carbonyl compounds with aldehydes.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Specifications

Chemical Identifiers

• CAS: 7791-03-9
• Molecular Formula: ClH6LiO7
• Molecular Weight (g/mol): 160.43
• MDL Number: MFCD00011079
• InChI Key: JAWYRNYHJJDXHX-UHFFFAOYSA-M
• Synonym: lithium perchlorate, perchloric acid, lithium salt, lithiumperchlorate, unii-q86se98c9c, lithium 1+ ion perchlorate, lithium perchlorate, anhydrous, lithium cloricum, lithium per chlorate, liclo4, perchloric acid, lithium salt 1:1
• PubChem CID: 23665649
• IUPAC Name: lithium;perchlorate
• SMILES: [Li+].[O-]Cl(=O)(=O)=O

• Boiling Point: 400°C (decomposition)
• Melting Point: 236°C
• Color: White
• Physical Form: Crystalline
• Quantity: 100 g
• Linear Formula: LiClO₄
• UN Number: UN1481
• Merck Index: 14,5539
• Solubility Information: Soluble in water,alcohol and ethyl acetate.
• Formula Weight: 106.4
• Percent Purity: ≤95.0%
• Grade: ACS
• Sensitivity: Hygroscopic
• Density: 2.43 g/mL
• Chemical Name or Material: Lithium perchlorate, Anhydrous

Safety and Handling

Signal Word

• Danger

Hazard Category

• Acute toxicity Category 4
• Serious eye damage/eye irritation Category 1
• Oxidising solid Category 1
• Skin corrosion/irritation Category 1 C

Hazard Statement

• H271-May cause fire or explosion; strong oxidiser.
• H302-Harmful if swallowed.
• H314-Causes severe skin burns and eye damage.
• H318-Causes serious eye damage.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P220-Keep/Store away from clothing/combustible materials.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.
• P371+P380+P375-In case of major fire and large quantities: Evacuate area Fight fire remotely due to the risk of explosion.

RUO – Research Use Only