Methyllithium, 1.6M sol. in diethyl ether (± 5% w/v), AcroSeal™, Thermo Scientific Chemicals

Product Code	Brand	Quantity	Packaging
10386212	Thermo Scientific Acros 188758000	800 mL	AcroSeal™ Glass Bottle

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Chemical Identifiers

• CAS: 917-54-4, 60-29-7
• Molecular Weight (g/mol): 21.98
• InChI Key: DVSDBMFJEQPWNO-UHFFFAOYSA-N
• PubChem CID: 2724049

• Molecular Formula: CH3Li
• MDL Number: MFCD00008253
• Synonym: methyllithium, lithium, methyl, methyl lithium, lithium methanide, meli, lithium methyl, lithium carbanide, lithium methide, methllithium, methyllithum
• SMILES: [Li]C

Specifications

• Color: Colorless to Yellow
• Molecular Formula: CH3Li
• MDL Number: MFCD00008253
• Density: 0.7000g/mL
• Solubility Information: Solubility in water: reacts.
• SMILES: [Li]C
• Molecular Weight (g/mol): 21.98
• Formula Weight: 21.96
• Specific Gravity: 0.7
• Physical Form: Solution

• CAS: 917-54-4, 60-29-7
• Linear Formula: CH₃Li
• Fieser: 01,686; 02,274; 03,202; 05,448; 06,384; 07,242; 08,342; 09,311; 11,340; 12,324; 16,219
• Synonym: methyllithium, lithium, methyl, methyl lithium, lithium methanide, meli, lithium methyl, lithium carbanide, lithium methide, methllithium, methyllithum
• InChI Key: DVSDBMFJEQPWNO-UHFFFAOYSA-N
• IUPAC Name: lithium;carbanide
• PubChem CID: 2724049
• Percent Purity: 4.5 to 5.5% (as MeLi)
• Flash Point: −17°C
• Chemical Name or Material: Methyllithium, Low Chloride, 1.6M Solution in Diethyl Ether (+/- 5% w/v)

Safety and Handling

GHS H Statement
Extremely flammable liquid and vapor. Catches fire spontaneously if exposed to air. In contact with water releases flammable gases which may ignite spontaneously. Causes severe skin burns and eye damage. May cause drowsiness or dizziness. Harmful if swallowed. Reacts violently with water. May form explosive peroxides. Repeated exposure may cause skin dryness or cracking.

GHS P Statement
Wear protective gloves/protective clothing/eye protection/face protection. Store in a dry place. Store in a closed container. IF ON SKIN: Gently wash with plenty of soap and water. IF SWALLOWED: rinse mouth. Do NOT induce vomiting. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell.

Danger

missing translation for 'einecsNumber' : 213-026-4

missing translation for 'tsca' : TSCA

Product Identifier

• Methyllithium, 1.6 M solution in diethyl ether

Signal Word

• Danger

Hazard Category

• Pyrophoric solid Category 1
• Substance which\, in contact with water\, emits flammable gases Category 1
• Flammable liquid Category 1
• Acute toxicity Category 4
• Skin corrosion/irritation Category 1 B
• Serious eye damage/eye irritation Category 1

Hazard Statement

• H224-Extremely flammable liquid and vapour.
• H250-Catches fire spontaneously if exposed to air.
• H260-In contact with water releases flammable gases which may ignite spontaneously.
• H302-Harmful if swallowed.
• H314-Causes severe skin burns and eye damage.
• H336-May cause drowsiness or dizziness.
• EUH014-Reacts violently with water.
• EUH019-May form explosive peroxides.
• EUH066-Repeated exposure may cause skin dryness or cracking.

Precautionary Statement

• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P402+P404-Store in a dry place. Store in a closed container.
• P302+P352-IF ON SKIN: Wash with plenty of water/.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P301+P312-IF SWALLOWED: Call a POISON CENTER or doctor/physician/ if you feel unwell.

Supplemental information

• MIXTURE LIST-Contains : Lithium, methyl-, Ethyl ether

RUO – Research Use Only