Methylmagnesium bromide, 3M solution in diethyl ether, AcroSeal™, Thermo Scientific Chemicals

Product Code	Brand	Quantity	Packaging
10434862	Thermo Scientific Acros 183541000	100 mL	AcroSeal™ Glass bottle
10097542	Thermo Scientific Acros 183548000	800 mL	AcroSeal™ Glass Bottle

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Chemical Identifiers

• CAS: 75-16-1, 60-29-7
• Molecular Weight (g/mol): 119.24
• InChI Key: AVFUHBJCUUTGCD-UHFFFAOYSA-M
• PubChem CID: 6349

• Molecular Formula: CH3BrMg
• MDL Number: MFCD00000041
• Synonym: methylmagnesium bromide, methyl magnesium bromide, magnesium, bromomethyl, bromo methyl magnesium, methylmagnesium bromide solution, 3.0 m in diethyl ether, unii-22cw9773df, memgbr, methymagnesiumbromide, ch3mgbr, methylmagnesiumbromide, grignard reagent
• SMILES: C[Mg]Br

Specifications

• Color: Colorless to Yellow
• Molecular Formula: CH3BrMg
• MDL Number: MFCD00000041
• Density: 1.0350g/mL
• Solubility Information: Solubility in water: vigorous reaction.
• SMILES: C[Mg]Br
• Molecular Weight (g/mol): 119.24
• Formula Weight: 119.26
• Flash Point: −40°C
• Chemical Name or Material: Methylmagnesium bromide, 3M Solution in Diethyl Ether

• CAS: 75-16-1, 60-29-7
• Linear Formula: CH₃MgBr
• Concentration: 2.85 to 3.20M
• Synonym: methylmagnesium bromide, methyl magnesium bromide, magnesium, bromomethyl, bromo methyl magnesium, methylmagnesium bromide solution, 3.0 m in diethyl ether, unii-22cw9773df, memgbr, methymagnesiumbromide, ch3mgbr, methylmagnesiumbromide, grignard reagent
• InChI Key: AVFUHBJCUUTGCD-UHFFFAOYSA-M
• IUPAC Name: magnesium;carbanide;bromide
• PubChem CID: 6349
• Specific Gravity: 1.035
• Physical Form: Solution, may develop some turbidity precipitate

Safety and Handling

GHS H Statement
Causes severe skin burns and eye damage. May cause drowsiness or dizziness. Harmful if swallowed. In contact with water releases flammable gases which may ignite spontaneously. Extremely flammable liquid and vapor. May form explosive peroxides. Reacts violently with water.

GHS P Statement
IF SWALLOWED: rinse mouth. Do NOT induce vomiting. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Immediately call a POISON CENTER or doctor/physician. Keep away from any possible contact with water, because of violent reaction and possible flash fire.

Danger

Product Identifier

• Methylmagnesium bromide, 3M solution in diethyl ether

Signal Word

• Danger

Hazard Category

• Flammable liquid Category 1
• Substance which\, in contact with water\, emits flammable gases Category 1
• Acute toxicity Category 4
• Specific target organ toxicity Category 3
• Skin corrosion/irritation Category 1 B
• Serious eye damage/eye irritation Category 1

Hazard Statement

• H224-Extremely flammable liquid and vapour.
• H260-In contact with water releases flammable gases which may ignite spontaneously.
• H314-Causes severe skin burns and eye damage.
• H336-May cause drowsiness or dizziness.
• H302-Harmful if swallowed.
• EUH019-May form explosive peroxides.
• EUH014-Reacts violently with water.

Precautionary Statement

• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P310-Immediately call a POISON CENTER/doctor/.
• P223-Do not allow contact with water.

Supplemental information

• MIXTURE LIST-Contains : Methyl magnesium bromide, Ethyl ether

RUO – Research Use Only