n-Butyllithium, 2.5M solution in hexanes, AcroSeal™, Thermo Scientific Chemicals

Product Code	Brand	Quantity	Packaging
16243861	Thermo Scientific Acros 213350500	50 mL	Glass bottle
10030462	Thermo Scientific Acros 213351000	100 mL	AcroSeal™ Glass bottle
10181852	Thermo Scientific Acros 213358000	800 mL	AcroSeal™ Glass Bottle

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Suitable for battery materials development.

Chemical Identifiers

• CAS: 109-72-8
• Molecular Weight (g/mol): 64.06
• InChI Key: MZRVEZGGRBJDDB-UHFFFAOYSA-N
• PubChem CID: 61028

• Molecular Formula: C4H9Li
• MDL Number: MFCD00009414
• Synonym: unii-09w9a6b8zc, buli, lithium, butyl, n-buli, n-butyllithium, n-butyl lithium, butyllithium, lithium butane, libu, butyl lithium
• SMILES: [Li]CCCC

Specifications

• CAS: 109-72-8
• Density: 0.6900 g/mL
• Flash Point: -21°C
• Linear Formula: CH₃(CH₂)₃Li
• Fieser: 01,95; 02,51; 04,60; 05,78; 06,85; 07,45; 08,65; 09,83; 10,68; 11,101; 12,96; 13,56; 14,63; 15,59; 16,55; 17,59
• Synonym: unii-09w9a6b8zc, buli, lithium, butyl, n-buli, n-butyllithium, n-butyl lithium, butyllithium, lithium butane, libu, butyl lithium
• SMILES: [Li]CCCC
• Molecular Weight (g/mol): 64.06
• Formula Weight: 64.06

• Melting Point: -95.0°C
• Boiling Point: 60.0°C to 80.0°C
• Molecular Formula: C4H9Li
• MDL Number: MFCD00009414
• Specific Gravity: 0.69
• InChI Key: MZRVEZGGRBJDDB-UHFFFAOYSA-N
• IUPAC Name: lithium(1+) butan-1-ide
• PubChem CID: 61028
• Chemical Name or Material: n-Butyllithium, 2.5 M Solution in Hexanes

Safety and Handling

GHS H Statement
Causes severe skin burns and eye damage. May be fatal if swallowed and enters airways. May cause damage to organs through prolonged or repeated exposure. Toxic to aquatic life with long lasting effects. May cause drowsiness or dizziness. Suspected of damaging fertility. Highly flammable liquid and vapor. Catches fire spontaneously if exposed to air. In contact with water releases flammable gases which may ignite spontaneously. Reacts violently with water.

GHS P Statement
IF SWALLOWED: rinse mouth. Do NOT induce vomiting. Wear eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Use personal protective equipment as required. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not allow contact with air. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not breathe dust/fume/gas/mist/vapors/spray. IF SWALLOWED: Immediately call a POISON CENTRE or doctor/physician. Do NOT induce vomiting. Avoid release to the environment. Store in a dry place. Store in a closed container. Ground/Bond container and receiving equipment. Take precautionary measures against static discharge.

Danger

missing translation for 'einecsNumber' : 203-698-7

missing translation for 'tsca' : TSCA

Signal Word

• Danger

Hazard Category

• LONG-TERM AQUATIC HAZARD Chronic 2
• Aspiration toxicity Category 1
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 2
• Pyrophoric liquid Category 1
• Reproductive toxicity Category 2
• Skin corrosion/irritation Category 1 B
• Specific target organ toxicity after repeated exposure Category 2
• Specific target organ toxicity Category 3
• Substance which\, in contact with water\, emits flammable gases Category 1

Hazard Statement

• H225-Highly flammable liquid and vapour.
• H250-Catches fire spontaneously if exposed to air.
• H260-In contact with water releases flammable gases which may ignite spontaneously.
• H304-May be fatal if swallowed and enters airways.
• H314-Causes severe skin burns and eye damage.
• H318-Causes serious eye damage.
• H336-May cause drowsiness or dizziness.
• H361f-Suspected of damaging fertility.
• H373-May cause damage to organs.
• H411-Toxic to aquatic life with long lasting effects.
• EUH014-Reacts violently with water.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P222-Do not allow contact with air.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P302+P352-IF ON SKIN: Wash with plenty of water/.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.

RUO – Research Use Only