n-Hexyllithium, 2.5M (33 wt.%) solution in hexane, AcroSeal™, Thermo Scientific Chemicals

Product Code	Brand	Quantity	Packaging
10369350	Thermo Scientific Acros 301651000	100 mL	AcroSeal™ Glass bottle
10115320	Thermo Scientific Acros 301658000	800 mL	AcroSeal™ Glass Bottle

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Chemical Identifiers

• CAS: 21369-64-2, 110-54-3
• Molecular Weight (g/mol): 92.11
• InChI Key: CETVQRFGPOGIQJ-UHFFFAOYSA-N
• PubChem CID: 2733163
• SMILES: [Li+].CCCCC[CH2-]

• Molecular Formula: C₆H₁₃Li
• MDL Number: MFCD00191446
• Synonym: n-hexyllithium, lithium, hexyl, hexyllithium, hexyl lithium, hexyl-lithium, lithium hexane, n-hexyllithiurn, n-hexyllitium, n-hexyl lithium, hexli
• IUPAC Name: lithium;hexane

Specifications

• CAS: 21369-64-2, 110-54-3
• CAS Max %: 33.2, 67.2
• Density: 0.6900g/mL
• Molecular Formula: C₆H₁₃Li
• MDL Number: MFCD00191446
• Synonym: n-hexyllithium, lithium, hexyl, hexyllithium, hexyl lithium, hexyl-lithium, lithium hexane, n-hexyllithiurn, n-hexyllitium, n-hexyl lithium, hexli
• InChI Key: CETVQRFGPOGIQJ-UHFFFAOYSA-N
• IUPAC Name: lithium;hexane
• PubChem CID: 2733163
• Percent Purity: 32.8 to 33.2% (as HexLi)
• Chemical Name or Material: n-Hexyllithium, 33 wt. % in n-hexane

• CAS Min %: 32.8, 66.8
• Color: Orange to Yellow
• Flash Point: −26°C
• Linear Formula: LiCH₂CH₂CH₂CH₂CH₂CH₃
• Specific Gravity: 0.69
• Solubility Information: Solubility in water: vigorous reaction.
• SMILES: [Li+].CCCCC[CH2-]
• Molecular Weight (g/mol): 92.11
• Formula Weight: 92.11
• Physical Form: Solution

Safety and Handling

GHS H Statement
Causes severe skin burns and eye damage.
May be fatal if swallowed and enters airways.
May cause drowsiness or dizziness.
Toxic to aquatic life with long lasting effects.
May cause damage to organs through p

GHS P Statement
IF SWALLOWED: Rinse mouth.
Do NOT induce vomiting.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses,if pre

GHS Signal Word: Danger

Product Identifier

• n-Hexyllithium, 33 wt.% solution in n-hexane

Signal Word

• Danger

Hazard Category

• Flammable liquid Category 2
• Substance which\, in contact with water\, emits flammable gases Category 1
• Pyrophoric liquid Category 1
• Aspiration toxicity Category 1
• Skin corrosion/irritation Category 1 A
• Serious eye damage/eye irritation Category 1
• Reproductive toxicity Category 2
• Specific target organ toxicity Category 3
• Specific target organ toxicity after repeated exposure Category 2
• LONG-TERM AQUATIC HAZARD Chronic 2

Hazard Statement

• H225-Highly flammable liquid and vapour.
• H250-Catches fire spontaneously if exposed to air.
• H260-In contact with water releases flammable gases which may ignite spontaneously.
• H304-May be fatal if swallowed and enters airways.
• H314-Causes severe skin burns and eye damage.
• H336-May cause drowsiness or dizziness.
• H361f-Suspected of damaging fertility.
• H373-May cause damage to organs.
• H411-Toxic to aquatic life with long lasting effects.
• EUH014-Reacts violently with water.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P231+P232-Handle under inert gas. Protect from moisture.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.

Supplemental information

• MIXTURE LIST-Contains : Hydrocarbons, C6, n-alkanes, isoalkanes,cyclics, 5-50% n-hexane, n-Hexyllithium

RUO – Research Use Only