Nitrosonium tetrafluoroborate, 98%

Codice prodotto. 11472468

missing translation for 'mfr': Thermo Scientific Alfa Aesar A15806.09

Descrizione

CAS: 14635-75-7 | BF4HNO2 | 133.82 g/mol

Nitrosonium tetrafluoroborate is a nitrosating agent and oxidizer used in organic synthesis. It is also used to convert arylamines directly to diazonium tetrafluoroborates, which undergo the Balz-Schiemann reaction in situ to give high yields of aryl fluorides. Further, it is used as a catalyst for iodination of aromatics by iodide ion with air as oxidant, conversion of secondary amines to nitrosamines and in deamination of primary amides. It is involved in the conversion of arylhydrazines to azides. In addition to this, it reacts with ferrocene to prepare ferrocenium tetrafluoroborate.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Nitrosonium tetrafluoroborate is a nitrosating agent and oxidizer used in organic synthesis. It is also used to convert arylamines directly to diazonium tetrafluoroborates, which undergo the Balz-Schiemann reaction in situ to give high yields of aryl fluorides. Further, it is used as a catalyst for iodination of aromatics by iodide ion with air as oxidant, conversion of secondary amines to nitrosamines and in deamination of primary amides. It is involved in the conversion of arylhydrazines to azides. In addition to this, it reacts with ferrocene to prepare ferrocenium tetrafluoroborate.

Solubility
Soluble in acetonitrile.

Notes
Hygroscopic. Air and moisture sensitive. Store in a cool place. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with acids and amines.

Specifica

Identificatori chimici

• CAS: 14635-75-7
• Molecular Formula: BF4HNO2
• Molecular Weight (g/mol): 133.82
• MDL Number: MFCD00011433
• InChI Key: XYRQURYIJKJVSF-UHFFFAOYSA-N
• Synonym: nitrosonium tetrafluoroborate, nitrosyl tetrafluoroborate, nitrosyltetrafluoroborate, nobf4, nitrilooxonium tetrafluoroborate, azanylidyneoxidanium tetrafluoroborate
• PubChem CID: 11137142
• IUPAC Name: azanylidyneoxidanium;tetrafluoroborate
• SMILES: [O-][NH+]=O.F[B-](F)(F)F

• Boiling Point: 250°C (0.01 mmHg)(Sublimation)
• Melting Point: 250°C (Sublimation)
• Quantity: 10 g
• UN Number: UN3260
• Merck Index: 14,6649
• Solubility Information: Soluble in acetonitrile.
• Formula Weight: 116.82
• Percent Purity: 98%
• Odor: Irritating
• Sensitivity: Moisture sensitive
• Density: 2.185
• Chemical Name or Material: Nitrosonium tetrafluoroborate

Sicurezza e movimentazione

Identificativo prodotto

• Nitrosonium tetrafluoroborate

Avvertenza

• Danger

Categoria di pericolo

• Serious eye damage/eye irritation Category 1
• Skin corrosion/irritation Category 1 B

Indicazioni di pericolo

• H314-Causes severe skin burns and eye damage.
• H318-Causes serious eye damage.
• EUH031-Contact with acids liberates toxic gas.

Consigli di prudenza

• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.

Informazioni supplementari

• MIXTURE LIST-Contains : Nitrosonium tetrafluoroborate

SDS

RUO – Research Use Only