p-Tolylmagnesium bromide, approx. 0.5M solution in diethyl ether, AcroSeal™, Thermo Scientific Chemicals

Description

p-Tolylmagnesium bromide, approx. 0.5M solution in diethyl ether, AcroSeal, Acros Organics, Quantity: 800mL, Packaging: AcroSeal Glass bottle, Molecular Weight: 195.34, CAS: 4294-57-9, 60-29-7, Density: 0.8660g/mL, Flash Point: -40 deg.C, Formula Weight: 195.34

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Specifications

Chemical Identifiers

• CAS: 4294-57-9, 60-29-7
• Molecular Formula: C7H7BrMg
• Molecular Weight (g/mol): 195.34
• MDL Number: MFCD00000040
• InChI Key: ZRJNGFJIBZKXTP-UHFFFAOYSA-M
• Synonym: p-tolylmagnesium bromide, magnesium, bromo 4-methylphenyl, 4-methylphenylmagnesium bromide, bromo 4-methylphenyl magnesium, 4-tolylmagnesium bromide, 4-toluylmagnesium bromide, p-tolyl-magnesium bromide, 4-tolyl magnesium bromide, 4-methylphenylmagnesiumbromide, p-methylphenylmagnesium bromide, grignard reagent
• PubChem CID: 3644322
• IUPAC Name: magnesium;methylbenzene;bromide
• SMILES: CC1=CC=C([Mg]Br)C=C1

• Density: 0.8660g/mL
• Flash Point: -40°C
• Packaging: AcroSeal™ Glass bottle
• Linear Formula: CH₃C₆H₄MgBr
• Quantity: 100 mL
• Specific Gravity: 0.866
• Formula Weight: 195.34
• Chemical Name or Material: p-Tolylmagnesium bromide

Safety and Handling

Product Identifier

• p-Tolylmagnesium bromide, ca. 0.4M(10%) solution in diethyl ether

Signal Word

• Danger

Hazard Category

• Acute toxicity Category 4
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 1
• Skin corrosion/irritation Category 1 B
• Specific target organ toxicity Category 3

Hazard Statement

• H318-Causes serious eye damage.
• H314-Causes severe skin burns and eye damage.
• H336-May cause drowsiness or dizziness.
• H302-Harmful if swallowed.
• H224-Extremely flammable liquid and vapour.
• EUH014-Reacts violently with water.
• EUH019-May form explosive peroxides.
• EUH066-Repeated exposure may cause skin dryness or cracking.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P233-Keep container tightly closed.
• P240-Ground/bond container and receiving equipment.
• P243-Take precautionary measures against static discharge.
• P261-Avoid breathing dust/fume/gas/mist/vapours/spray.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P312-IF SWALLOWED: Call a POISON CENTER or doctor/physician/ if you feel unwell.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.
• P402+P404-Store in a dry place. Store in a closed container.
• P403+P235-Store in a well-ventilated place. Keep cool.

RUO – Research Use Only