Phenyl formate, 95%, Thermo Scientific Chemicals

Product Code	Brand	Quantity
11369973	Thermo Scientific Alfa Aesar L00289.06	5 g
11379973	Thermo Scientific Alfa Aesar L00289.14	25 g

Description

Phenyl formate is widely used in the palladium-catalyzed carbonylation of aryl, alkenyl and allyl halides. It is also used as a reagent for the formylation of amines.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Phenyl formate is widely used in the palladium-catalyzed carbonylation of aryl, alkenyl and allyl halides. It is also used as a reagent for the formylation of amines.

Solubility
Immiscible with water, alcohol, ether and benzene.

Chemical Identifiers

• CAS: 1864-94-4
• Molecular Weight (g/mol): 122.123
• InChI Key: GEOWCLRLLWTHDN-UHFFFAOYSA-N
• PubChem CID: 74626
• SMILES: C1=CC=C(C=C1)OC=O

• Molecular Formula: C7H6O2
• MDL Number: MFCD00014126
• Synonym: formic acid phenyl ester, formic acid, phenyl ester, phocho, formic acid, phenylester, acmc-1box2, phenyl formate gc
• IUPAC Name: phenyl formate

Specifications

• CAS: 1864-94-4
• Boiling Point: 72°C to 74°C (13 mmHg)
• Molecular Formula: C7H6O2
• MDL Number: MFCD00014126
• Synonym: formic acid phenyl ester, formic acid, phenyl ester, phocho, formic acid, phenylester, acmc-1box2, phenyl formate gc
• InChI Key: GEOWCLRLLWTHDN-UHFFFAOYSA-N
• IUPAC Name: phenyl formate
• PubChem CID: 74626
• Percent Purity: 95%

• Density: 1.09
• Flash Point: 71°C (159°F)
• Refractive Index: 1.512
• Beilstein: 507113
• Solubility Information: Immiscible with water,alcohol,ether and benzene.
• SMILES: C1=CC=C(C=C1)OC=O
• Molecular Weight (g/mol): 122.123
• Formula Weight: 122.12
• Chemical Name or Material: Phenyl formate

Safety and Handling

GHS H Statement
H315-H319-H335-H227
Causes skin irritation.
Causes serious eye irritation.
May cause respiratory irritation.
Combustible liquid.

P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P362-P501c

H315-H319-H335

missing translation for 'einecsNumber' : 217-471-5

missing translation for 'tsca' : No

Recommended Storage : Ambient temperatures

Signal Word

• Warning

Hazard Category

• Serious eye damage/eye irritation Category 2
• Skin corrosion/irritation Category 2
• Specific target organ toxicity Category 3

Hazard Statement

• H315-Causes skin irritation.
• H319-Causes serious eye irritation.
• H335-May cause respiratory irritation.

Precautionary Statement

• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P302+P352-IF ON SKIN: Wash with plenty of water/.
• P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
• P312-Call a POISON CENTER/doctor/if you feel unwell.
• P332+P313-If skin irritation occurs: Get medical advice/attention.
• P337+P313-If eye irritation persists: Get medical advice/attention.

RUO – Research Use Only