Phosphorus tribromide, 99%, Thermo Scientific Chemicals

Product Code	Brand	Quantity	Packaging
10092180	Thermo Scientific Acros 169470050	5 g	Glass bottle
10669253	Thermo Scientific Acros 169471000	100 g	Glass bottle
10677332	Thermo Scientific Acros 169475000	500 g	Glass bottle

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

C-X bond formation reagent

Chemical Identifiers

• CAS: 7789-60-8
• Molecular Weight (g/mol): 270.69
• InChI Key: IPNPIHIZVLFAFP-UHFFFAOYSA-N
• PubChem CID: 24614
• SMILES: P(Br)(Br)Br

• Molecular Formula: Br₃P
• MDL Number: MFCD00011436
• Synonym: phosphorus tribromide, phosphorous tribromide, tribromophosphine, phosphorus iii bromide, phosphorous bromide, pbr3, phosphorus bromide, phosphorus bromide pbr3, unii-58r3866pua, tribro-mophosphine
• IUPAC Name: tribromophosphane

Specifications

• Boiling Point: 175.0°C
• CAS: 7789-60-8
• Physical Form: Liquid
• Molecular Formula: Br₃P
• MDL Number: MFCD00011436
• Merck Index: 15, 7469
• Solubility Information: Solubility in water: reacts. Other solubilities: soluble in acetone, alcohol, carbon disulfide,, hydrogen sulfide, methanol, ether, chloroform and, carbon tetrachloride
• SMILES: P(Br)(Br)Br
• Molecular Weight (g/mol): 270.69
• Formula Weight: 270.69
• Refractive Index: 1.697
• Density: 2.8800g/mL

• Melting Point: -40.0°C
• Color: Brown or Colorless to Yellow
• Assay Percent Range: 98.5% min. (ex Br) (Argentometry)
• Linear Formula: PBr₃
• Fieser: 01,873; 02,330; 07,292
• Synonym: phosphorus tribromide, phosphorous tribromide, tribromophosphine, phosphorus iii bromide, phosphorous bromide, pbr3, phosphorus bromide, phosphorus bromide pbr3, unii-58r3866pua, tribro-mophosphine
• InChI Key: IPNPIHIZVLFAFP-UHFFFAOYSA-N
• IUPAC Name: tribromophosphane
• PubChem CID: 24614
• Percent Purity: 99%
• Specific Gravity: 2.88
• Chemical Name or Material: Phosphorus tribromide

Safety and Handling

GHS H Statement
Causes severe skin burns and eye damage.
May cause respiratory irritation.
Reacts violently with water.

GHS P Statement
IF SWALLOWED: rinse mouth.
Do NOT induce vomiting.
Wear protective gloves/protective clothing/eye protection/face protection.
IF IN EYES: Rinse cautiously with water for several minutes.
Remove contact lenses,if pre

GHS Signal Word: Danger

missing translation for 'einecsNumber' : 232-178-2

Product Identifier

• Phosphorus tribromide

Signal Word

• Danger

Hazard Category

• Serious eye damage/eye irritation Category 1
• Skin corrosion/irritation Category 1 B
• Specific target organ toxicity Category 3

Hazard Statement

• H318-Causes serious eye damage.
• H335-May cause respiratory irritation.
• H314-Causes severe skin burns and eye damage.
• EUH014-Reacts violently with water.

Precautionary Statement

• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.

RUO – Research Use Only