Propargyl bromide, 80wt.% solution in toluene, stabilized, AcroSeal™, Thermo Scientific Chemicals

Product Code	Brand	Quantity	Packaging
10166924	Thermo Scientific Acros 429121000	100 mL	AcroSeal™ Glass Bottle
15179293	Thermo Scientific Acros 429120010	1 L	AcroSeal™ Glass Bottle

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Alkylation reagent

Specifications

• Boiling Point: 88.0°C to 90.0°C
• Name Note: Stabilized
• Color: White to Yellow
• Molecular Formula: C₃H₃Br
• MDL Number: MFCD00000241
• Synonym: propargyl bromide, 3-bromopropyne, 3-bromo-1-propyne, 1-propyne, 3-bromo, 2-propynyl bromide, propynyl bromide, 1-bromo-2-propyne, propyne, 3-bromo, gamma-bromoallylene, 1-brom-2-propin
• InChI Key: YORCIIVHUBAYBQ-UHFFFAOYSA-N
• IUPAC Name: 3-bromoprop-1-yne
• PubChem CID: 7842
• Percent Purity: 73 to 87% (propargyl bromide) (GC), 13 to 27% (toluene) (GC)
• Refractive Index: 1.4900 to 1.4960
• Density: 1.3800g/mL

• Chemical Name or Material: Propargyl bromide
• CAS: 106-96-7, 108-88-3
• Physical Form: Crystalline Powder
• Linear Formula: HC≡CCH₂Br
• Flash Point: 4°C
• Solubility Information: Solubility in water: immiscible
• SMILES: C#CCBr
• Molecular Weight (g/mol): 118.96
• Formula Weight: 118.96
• Packaging: AcroSeal™ Glass Bottle
• Specific Gravity: 1.38

Safety and Handling

GHS H Statement
May cause damage to organs through prolonged or repeated exposure. Suspected of damaging fertility or the unborn child. May cause drowsiness or dizziness. May be fatal if swallowed and enters airways. Causes severe skin burns and eye damage. Toxic if swallowed. Highly flammable liquid and vapor.

GHS P Statement
Use personal protective equipment as required. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not breathe dust/fume/gas/mist/vapors/spray. IF SWALLOWED: Immediately call a POISON CENTRE or doctor/physician. Do NOT induce vomiting. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. IF ON SKIN: Wash with plenty of soap and water. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/Bond container and receiving equipment.

GHS Signal Word: Danger

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Product Identifier

• Propargyl bromide, 80 wt% solution in toluene, stabilized

Signal Word

• Danger

Hazard Category

• Acute toxicity Category 3
• Aspiration toxicity Category 1
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 2
• Reproductive toxicity Category 2
• Skin corrosion/irritation Category 1 B
• Specific target organ toxicity after repeated exposure Category 2
• Specific target organ toxicity Category 3

Hazard Statement

• H304-May be fatal if swallowed and enters airways.
• H318-Causes serious eye damage.
• H314-Causes severe skin burns and eye damage.
• H361-Suspected of damaging fertility or the unborn child.
• H373-May cause damage to organs.
• H331-Toxic if inhaled.
• H336-May cause drowsiness or dizziness.
• H225-Highly flammable liquid and vapour.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P240-Ground/bond container and receiving equipment.
• P260-Do not breathe dust/fume/gas/mist/vapours/spray.
• P261-Avoid breathing dust/fume/gas/mist/vapours/spray.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P310-IF SWALLOWED: Immediately call a POISON CENTER/doctor /
• P302+P352-IF ON SKIN: Wash with plenty of water/.
• P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
• P331-Do NOT induce vomiting.

RUO – Research Use Only