sec-Butyllithium, 1.3M sol. in cyclohexane/hexane (92/8), AcroSeal™, Thermo Scientific Chemicals

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Specifications

Chemical Identifiers

• CAS: 598-30-1, 110-82-7, 110-54-3
• Molecular Formula: C4H9Li
• Molecular Weight (g/mol): 64.06
• MDL Number: MFCD00009323
• InChI Key: VATDYQWILMGLEW-UHFFFAOYNA-N
• Synonym: sec-butyllithium, s-buli, s-butyllithium, s-butyl lithium, unii-5yv3gii1tb, lithium, 1-methylpropyl, 5yv3gii1tb, secbutyllithium, b-butyllithium, sec-butyllitium
• PubChem CID: 102446
• IUPAC Name: (butan-2-yl)lithium
• SMILES: [Li]C(C)CC

• Color: Colorless
• Linear Formula: C₂H₅CH(CH₃)Li
• Fieser: 09,87; 10,75; 12,97; 16,56
• Density: 0.7500g/mL
• Solubility Information: Solubility in water: reacts (forming lioh and butane).
• Formula Weight: 64.06
• Percent Purity: 10.5 to 12.5% (as BuLi) (Active base)
• Packaging: AcroSeal™ Glass bottle
• Specific Gravity: 0.75
• Quantity: 100 mL
• Flash Point: −17°C
• Physical Form: Liquid
• Chemical Name or Material: sec-Butyllithium, 1.3M Solution in Cyclohexane/hexane (92/8)

Safety and Handling

Product Identifier

• sec-Butyllithium, 1.3M solution in cyclohexane/hexane (92/8)

Signal Word

• Danger

Hazard Category

• Aspiration toxicity Category 1
• Pyrophoric solid Category 1
• Substance which\, in contact with water\, emits flammable gases Category 1
• Flammable liquid Category 2
• Skin corrosion/irritation Category 1 B
• Reproductive toxicity Category 2
• ACUTE AQUATIC Acute 1
• LONG-TERM AQUATIC HAZARD Chronic 1
• Specific target organ toxicity Category 3
• Specific target organ toxicity after repeated exposure Category 2

Hazard Statement

• H225-Highly flammable liquid and vapour.
• H250-Catches fire spontaneously if exposed to air.
• H260-In contact with water releases flammable gases which may ignite spontaneously.
• H336-May cause drowsiness or dizziness.
• H410-Very toxic to aquatic life with long lasting effects.
• H314-Causes severe skin burns and eye damage.
• H304-May be fatal if swallowed and enters airways.
• H361f-Suspected of damaging fertility.
• H373-May cause damage to organs.
• EUH014-Reacts violently with water.

Precautionary Statement

• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.
• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P222-Do not allow contact with air.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P260-Do not breathe dust/fume/gas/mist/vapours/spray.

Supplemental information

• MIXTURE LIST-Contains : Hexane, Lithium, (1-methylpropyl), Cyclohexane

RUO – Research Use Only