Tebbe reagent, 0.5M solution in toluene, Thermo Scientific Chemicals

Product Code	Brand	Quantity	Packaging
10772263	Thermo Scientific Acros 368970250	25 mL	Glass Bottle
10089001	Thermo Scientific Acros 368971000	100 mL	AcroSeal™ Glass bottle

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

For C-C Bond Formation (Olefination), Lewis acid

Specifications

• Chemical Name or Material: Tebbe reagent
• CAS: 67719-69-1, 108-88-3
• Density: 0.9270g/mL
• Molecular Formula: C₁₃H₁₈AlClTi
• Fieser: 08,83; 10,87; 11,52; 12,54; 13,71; 15,79; 16,70; 17,69
• Synonym: Bis(cyclopentadienyl-μ-chloro(dimethylaluminum-μ-methylenetitanium
• Formula Weight: 284.62

• Name Note: 0.5M solution in toluene
• Color: Purple to Red
• Flash Point: 4°C
• MDL Number: MFCD00151575
• Specific Gravity: 0.927
• Solubility Information: Solubility in water: reacts.
• Physical Form: Solution

Safety and Handling

GHS H Statement
Causes severe skin burns and eye damage. May cause damage to organs through prolonged or repeated exposure. May be fatal if swallowed and enters airways. May cause drowsiness or dizziness. Suspected of damaging fertility or the unborn child. Highly flammable liquid and vapor.

GHS P Statement
IF SWALLOWED: rinse mouth. Do NOT induce vomiting. Wear eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Use personal protective equipment as required. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not breathe dust/fume/gas/mist/vapors/spray. IF SWALLOWED: Immediately call a POISON CENTRE or doctor/physician. Do NOT induce vomiting. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Ground/Bond container and receiving equipment.

Danger

Product Identifier

• Tebbe reagent, 0.5M solution in toluene

Signal Word

• Danger

Hazard Category

• Aspiration toxicity Category 1
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 2
• Reproductive toxicity Category 2
• Skin corrosion/irritation Category 1 B
• Specific target organ toxicity after repeated exposure Category 2
• Specific target organ toxicity Category 3

Hazard Statement

• H304-May be fatal if swallowed and enters airways.
• H318-Causes serious eye damage.
• H314-Causes severe skin burns and eye damage.
• H361-Suspected of damaging fertility or the unborn child.
• H373-May cause damage to organs.
• H336-May cause drowsiness or dizziness.
• H225-Highly flammable liquid and vapour.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P240-Ground/bond container and receiving equipment.
• P260-Do not breathe dust/fume/gas/mist/vapours/spray.
• P261-Avoid breathing dust/fume/gas/mist/vapours/spray.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P310-IF SWALLOWED: Immediately call a POISON CENTER/doctor /
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.
• P331-Do NOT induce vomiting.

RUO – Research Use Only