Titanium(III) chloride tetrahydrofuran complex, 97%, Thermo Scientific Chemicals

Product Code	Brand	Quantity	Packaging
10525983	Thermo Scientific Acros 375160010	1 g	Glass bottle
10598663	Thermo Scientific Acros 375160100	10 g	Glass Bottle

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Reduction reagent

Chemical Identifiers

• CAS: 18039-90-2
• Molecular Weight (g/mol): 370.56
• InChI Key: MIDYWIPTCYRMQF-UHFFFAOYSA-K
• PubChem CID: 6097232
• SMILES: C1CCOC1.C1CCOC1.C1CCOC1.Cl[Ti](Cl)Cl

• Molecular Formula: C₁₂H₂₄Cl₃O₃Ti
• MDL Number: MFCD01631276
• Synonym: oxolane; trichlorotitanium, titanium iii chloride tetrahydrofuran complex 1:3, trichlorotris thf titanium, titanium trichloride tri thf, trichlorotris tetrahydrofuran titanium, thf-titanium trichloride complex, 3:1, titanium trichloride tris tetrahydrofuran, trichlorotris tetrahydrofuran titanium iii, trichlorotris tetrahydrofuran tita-nium iii, titanium trichloride tetrahydrofuran complex 1:3
• IUPAC Name: oxolane;trichlorotitanium

Specifications

• Melting Point: >250°C
• Color: Blue to Blue-Green
• Assay Percent Range: 96% min. (Argentometry)
• MDL Number: MFCD01631276
• Solubility Information: Solubility in water: reacts violently
• SMILES: C1CCOC1.C1CCOC1.C1CCOC1.Cl[Ti](Cl)Cl
• Molecular Weight (g/mol): 370.56
• Formula Weight: 370.56
• Infrared Spectrum: Authentic

• CAS: 18039-90-2
• Physical Form: Crystals or Powder
• Molecular Formula: C₁₂H₂₄Cl₃O₃Ti
• Synonym: oxolane; trichlorotitanium, titanium iii chloride tetrahydrofuran complex 1:3, trichlorotris thf titanium, titanium trichloride tri thf, trichlorotris tetrahydrofuran titanium, thf-titanium trichloride complex, 3:1, titanium trichloride tris tetrahydrofuran, trichlorotris tetrahydrofuran titanium iii, trichlorotris tetrahydrofuran tita-nium iii, titanium trichloride tetrahydrofuran complex 1:3
• InChI Key: MIDYWIPTCYRMQF-UHFFFAOYSA-K
• IUPAC Name: oxolane;trichlorotitanium
• PubChem CID: 6097232
• Percent Purity: 97%
• Chemical Name or Material: Titanium(III) chloride tetrahydrofuran complex

Safety and Handling

GHS H Statement:
Flammable solid.
Causes serious eye damage.
Reacts violently with water.
May form explosive peroxides.
Contact with water liberates toxic gas.

GHS P Statement:
Keep away from heat/sparks/open flames/hot surfaces. - No smoking.
Wear eye protection/face protection.
IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Immediately call a POISON CENTER or doctor/physician.

WARNING: The information provided on this web site was developed in compliance with European Union (EU) regulations and is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guide for safe handling and use. It is not to be considered as either a warranty or quality specification.

GHS Signal Word: Danger

Product Identifier

• Titanium(III) chloride tetrahydrofuran complex

Signal Word

• Danger

Hazard Category

• Flammable solid Category 2
• Skin corrosion/irritation Category 1 B

Hazard Statement

• H314-Causes severe skin burns and eye damage.
• H228-Flammable solid.
• EUH014-Reacts violently with water.
• EUH019-May form explosive peroxides.
• EUH029-Contact with water liberates toxic gas.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.

RUO – Research Use Only