Triethylsilane, 98+%, Thermo Scientific Chemicals

Description

Triethylsilane is used for the hydrosilation of olefins to prepare alkyl silanes. It acts as a reducing agent in the reduction of 2-chromanols, since it has an active hydride. It acts as a catalyst for redox initiated cationic polymerization, regioselective reductive coupling of enones and allenes, and Beckmann rearrangement of cyclododecanone oxime. It is associated with trifluoroacetic acid and involved in the selective reduction of alkenes.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Triethylsilane is used for the hydrosilation of olefins to prepare alkyl silanes. It acts as a reducing agent in the reduction of 2-chromanols, since it has an active hydride. It acts as a catalyst for redox initiated cationic polymerization, regioselective reductive coupling of enones and allenes, and Beckmann rearrangement of cyclododecanone oxime. It is associated with trifluoroacetic acid and involved in the selective reduction of alkenes.

Solubility
Miscible with water.

Notes
Incompatible with strong acids, water and bases.

Specifications

Chemical Identifiers

• CAS: 617-86-7
• Molecular Formula: C6H15Si
• Molecular Weight (g/mol): 115.271
• MDL Number: MFCD00009018
• InChI Key: QXTIBZLKQPJVII-UHFFFAOYSA-N
• Synonym: triethylsilane, hydride, silane, triethyl, triethylhydrosilane, triethylsilyl, silane e3h, c6h16si, triethylsilyl radical, silane, triethyl-,, triethylsilane tes
• PubChem CID: 6327258
• IUPAC Name: triethylsilicon
• SMILES: CC[Si](CC)CC

• Boiling Point: 107°C to 108°C
• Melting Point: -157°C
• Quantity: 50 g
• Linear Formula: (CH₃CH₂)₃SiH
• UN Number: UN1993
• Beilstein: 1098278
• Flash Point: −6°C (21°F)
• Solubility Information: Miscible with water.
• Formula Weight: 116.28
• Percent Purity: ≥98%
• Refractive Index: 1.412
• Sensitivity: Moisture sensitive
• Density: 0.728
• Chemical Name or Material: Triethylsilane

Safety and Handling

Signal Word

• Danger

Hazard Category

• LONG-TERM AQUATIC HAZARD Chronic 1
• ACUTE AQUATIC Acute 1
• Flammable liquid Category 2

Hazard Statement

• H225-Highly flammable liquid and vapour.
• H400-Very toxic to aquatic life.
• H410-Very toxic to aquatic life with long lasting effects.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P403+P233-Store in a well-ventilated place. Keep container tightly closed.

RUO – Research Use Only