Tris(2-dimethylaminoethyl)amine, 98+%, Thermo Scientific Chemicals

Product Code	Brand	Quantity
15424507	Thermo Scientific Alfa Aesar H31853.06	5 g
15434507	Thermo Scientific Alfa Aesar H31853.14	25 g

Description

Tris(2-dimethylaminoethyl)amine is used as an atom transfer radical polymerization (ATRP) ligand for the creation of telechelic polymers. It is a tripodal polyamine ligand and forms complexes with group 1 metals, which is used in alkali-metal-mediated synthetic applications. Further, it is involved in the macrocyclization processes by reacting with tripodal esters in methanol to give tricyclic cryptands.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Tris(2-dimethylaminoethyl)amine is used as an atom transfer radical polymerization (ATRP) ligand for the creation of telechelic polymers. It is a tripodal polyamine ligand and forms complexes with group 1 metals, which is used in alkali-metal-mediated synthetic applications. Further, it is involved in the macrocyclization processes by reacting with tripodal esters in methanol to give tricyclic cryptands.

Solubility
Miscible with water.

Notes
Hygroscopic. Air sensitive. Incompatible with oxidizing agents, acids.

Chemical Identifiers

• CAS: 33527-91-2
• Molecular Weight (g/mol): 230.40
• InChI Key: VMGSQCIDWAUGLQ-UHFFFAOYSA-N
• PubChem CID: 263094
• SMILES: CN(C)CCN(CCN(C)C)CCN(C)C

• Molecular Formula: C12H30N4
• MDL Number: MFCD00015607
• Synonym: n1,n1-bis 2-dimethylamino ethyl-n2,n2-dimethylethane-1,2-diamine, tris 2-dimethylaminoethyl amine, tris 2-dimethylamino ethyl amine, me6tren, 1,2-ethanediamine, n,n-bis 2-dimethylamino ethyl-n',n'-dimethyl, 2-bis 2-dimethylamino ethyl amino ethyl dimethylamine, acmc-20ah4b, n,n-bis 2-dimethylamino ethyl-n',n'-dimethylethane-1,2-diamine
• IUPAC Name: N',N'-bis[2-(dimethylamino)ethyl]-N,N-dimethylethane-1,2-diamine

Specifications

• CAS: 33527-91-2
• Molecular Formula: C12H30N4
• Refractive Index: 1.454
• UN Number: UN2735
• Synonym: n1,n1-bis 2-dimethylamino ethyl-n2,n2-dimethylethane-1,2-diamine, tris 2-dimethylaminoethyl amine, tris 2-dimethylamino ethyl amine, me6tren, 1,2-ethanediamine, n,n-bis 2-dimethylamino ethyl-n',n'-dimethyl, 2-bis 2-dimethylamino ethyl amino ethyl dimethylamine, acmc-20ah4b, n,n-bis 2-dimethylamino ethyl-n',n'-dimethylethane-1,2-diamine
• InChI Key: VMGSQCIDWAUGLQ-UHFFFAOYSA-N
• IUPAC Name: N',N'-bis[2-(dimethylamino)ethyl]-N,N-dimethylethane-1,2-diamine
• PubChem CID: 263094
• Percent Purity: ≥99%

• Boiling Point: 70°C to 71°C (0.5 mmHg)
• Linear Formula: [(CH₃)₂NCH₂CH₂]₃N
• MDL Number: MFCD00015607
• Sensitivity: Air sensitive; Hygroscopic
• Solubility Information: Miscible with water.
• SMILES: CN(C)CCN(CCN(C)C)CCN(C)C
• Molecular Weight (g/mol): 230.40
• Formula Weight: 230.4
• Chemical Name or Material: Tris(2-dimethylaminoethyl)amine

Safety and Handling

GHS H Statement
H314-H318
Causes severe skin burns and eye damage.
Causes serious eye damage.

P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

H314-H335

missing translation for 'dotInformation' : Transport Hazard Class: 8; Packing Group: III; Proper Shipping Name: AMINES, LIQUID, CORROSIVE, N.O.S.

missing translation for 'tsca' : Yes

Recommended Storage : Ambient temperatures; Store under Nitrogen

Product Identifier

• Tris(2-dimethylaminoethyl)amine

Signal Word

• Danger

Hazard Category

• Serious eye damage/eye irritation Category 1
• Skin corrosion/irritation Category 1 B

Hazard Statement

• H314-Causes severe skin burns and eye damage.
• H318-Causes serious eye damage.

Precautionary Statement

• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.

Supplemental information

• MIXTURE LIST-Contains : Tris(2-dimethylaminoethyl)amine

RUO – Research Use Only