Borane-tetrahydrofuran complex, 1M solution in THF, Stabilized, AcroSeal™, Thermo Scientific Chemicals

Product Code	Brand	Quantity	Packaging
10781641	Thermo Scientific Acros 175081000	100 mL	AcroSeal™ Glass bottle
10781831	Thermo Scientific Acros 175088000	800 mL	AcroSeal™ Glass bottle

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Reduction reagent

Specifications

• Chemical Name or Material: Borane-tetrahydrofuran complex
• Name Note: 1M solution in tetrahydrofuran, stabilized
• Molecular Formula: C4H11BO
• Concentration: 0.96 to 1.08M
• Density: 0.8760g/mL
• Synonym: borane-tetrahydrofuran complex, tetrahydrofuran borane, bh3.thf, borane tetrahydrofuran complex solution, borane-d3-thf complex solution, borane-tetrahydrofuran, unii-5ear4err1l, oxolane borane, boron; oxolane, borane thf
• InChI Key: RMCYTHFAWCWRFA-UHFFFAOYSA-N
• IUPAC Name: oxolane borane
• PubChem CID: 11062302
• Packaging: AcroSeal™ Glass bottle
• Treatment(s): Stabilized
• Physical Form: Liquid

• Color: Colorless
• CAS: 14044-65-6, 109-99-9
• MDL Number: MFCD00012429
• Fieser: 01,199; 02,106; 03,76; 04,124; 05,184; 06,161; 07,89; 12,65; 17,101
• Merck Index: 15, 1336
• Solubility Information: Solubility in water: reacts.
• SMILES: B.C1CCOC1
• Molecular Weight (g/mol): 85.94
• Formula Weight: 85.94
• Specific Gravity: 0.876
• Flash Point: −22°C

Safety and Handling

GHS H Statement
May cause respiratory irritation. Causes serious eye damage. In contact with water releases flammable gases which may ignite spontaneously. Causes skin irritation. Harmful if swallowed. Highly flammable liquid and vapour. Suspected of causing cancer. Reacts violently with water. May form explosive peroxides. May cause drowsiness or dizziness.

GHS P Statement
Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. Handle under inert gas. Protect from moisture. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: rinse mouth. Do NOT induce vomiting. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.

Danger

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Product Identifier

• Borane-tetrahydrofuran complex, 1M solution in THF, stabilized

Signal Word

• Danger

Hazard Category

• Acute toxicity Category 4
• Carcinogenicity Category 2
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 2
• Skin corrosion/irritation Category 2
• Specific target organ toxicity Category 3
• Substance which\, in contact with water\, emits flammable gases Category 1

Hazard Statement

• H318-Causes serious eye damage.
• H315-Causes skin irritation.
• H351-Suspected of causing cancer.
• H335-May cause respiratory irritation.
• H336-May cause drowsiness or dizziness.
• H302-Harmful if swallowed.
• H260-In contact with water releases flammable gases which may ignite spontaneously.
• H225-Highly flammable liquid and vapour.
• EUH014-Reacts violently with water.
• EUH019-May form explosive peroxides.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P231+P232-Handle under inert gas. Protect from moisture.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.

Supplemental information

• MIXTURE LIST-Contains : Tetrahydrofuran, Borane-tetrahydrofurancomplex

RUO – Research Use Only