Ethylaluminium sesquichloride, 0.4M solution in hexane, AcroSeal™, Thermo Scientific Chemicals

Product Code	Brand	Quantity	Packaging
10220793	Thermo Scientific Acros 185461000	100 mL	AcroSeal™ Glass Bottle
10311803	Thermo Scientific Acros 185468000	800 mL	AcroSeal™ Glass Bottle

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Lewis acid

Chemical Identifiers

• CAS: 12075-68-2, 110-54-3
• Molecular Weight (g/mol): 247.51
• InChI Key: LDXMUMPEDOQULK-UHFFFAOYSA-K
• PubChem CID: 25508
• SMILES: CC[Al](CC)Cl.CC[Al](Cl)Cl

• Molecular Formula: C₆H₁₅Al₂Cl₃
• MDL Number: MFCD00044852
• Synonym: ethylaluminum sesquichloride, ethylaluminium sesquichloride, sesquiethylaluminum chloride, easc, aluminum, trichlorotriethyldi, ethylaluminum sesquichioride, ethylaluminum sesquichloride solution, di-, i-chlorochlorotriethyldi-aluminum, chloro diethyl alumane; dichloro ethyl alumane
• IUPAC Name: chloro(diethyl)alumane;dichloro(ethyl)alumane

Specifications

• CAS: 12075-68-2, 110-54-3
• Density: 0.7010g/mL
• Molecular Formula: C₆H₁₅Al₂Cl₃
• MDL Number: MFCD00044852
• Synonym: ethylaluminum sesquichloride, ethylaluminium sesquichloride, sesquiethylaluminum chloride, easc, aluminum, trichlorotriethyldi, ethylaluminum sesquichioride, ethylaluminum sesquichloride solution, di-, i-chlorochlorotriethyldi-aluminum, chloro diethyl alumane; dichloro ethyl alumane
• InChI Key: LDXMUMPEDOQULK-UHFFFAOYSA-K
• IUPAC Name: chloro(diethyl)alumane;dichloro(ethyl)alumane
• PubChem CID: 25508
• Percent Purity: 14.5 to 15.5% (on Al basis)
• Chemical Name or Material: Ethylaluminium sesquichloride

• Color: Colorless
• Flash Point: -22°C
• Linear Formula: (C₂H₅)₂AlCl·Cl₂AlC₂H₅
• Specific Gravity: 0.701
• Solubility Information: Solubility in water: vigorous reaction. Other solubilities: miscible with saturated aliphatic and aromatic,hydrocarbons
• SMILES: CC[Al](CC)Cl.CC[Al](Cl)Cl
• Molecular Weight (g/mol): 247.51
• Formula Weight: 247.51
• Physical Form: Liquid

Safety and Handling

GHS H Statement
May cause damage to organs through prolonged or repeated exposure.
May cause drowsiness or dizziness.
May be fatal if swallowed and enters airways.
Toxic to aquatic life with long lasting effects.
Suspected

GHS P Statement
Use personal protective equipment as required.
Avoid breathing dust/fume/gas/mist/vapors/spray.
Do not breathe dust/fume/gas/mist/vapors/spray.
IF SWALLOWED: Immediately call a POISON CENTRE or doctor/physician.

GHS Signal Word: Danger

missing translation for 'einecsNumber' : 235-137-7

Product Identifier

• Ethylaluminium sesquichloride, 0.4M solution in hexane

Signal Word

• Danger

Hazard Category

• LONG-TERM AQUATIC HAZARD Chronic 2
• Aspiration toxicity Category 1
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 2
• Reproductive toxicity Category 2
• Skin corrosion/irritation Category 1 A
• Specific target organ toxicity after repeated exposure Category 2
• Specific target organ toxicity Category 3
• Substance which\, in contact with water\, emits flammable gases Category 1

Hazard Statement

• H304-May be fatal if swallowed and enters airways.
• H318-Causes serious eye damage.
• H314-Causes severe skin burns and eye damage.
• H361f-Suspected of damaging fertility.
• H373-May cause damage to organs.
• H411-Toxic to aquatic life with long lasting effects.
• H336-May cause drowsiness or dizziness.
• H260-In contact with water releases flammable gases which may ignite spontaneously.
• H225-Highly flammable liquid and vapour.
• EUH014-Reacts violently with water.

Precautionary Statement

• P260-Do not breathe dust/fume/gas/mist/vapours/spray.
• P261-Avoid breathing dust/fume/gas/mist/vapours/spray.
• P273-Avoid release to the environment.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P310-IF SWALLOWED: Immediately call a POISON CENTER/doctor /
• P302+P352-IF ON SKIN: Wash with plenty of water/.
• P331-Do NOT induce vomiting.

RUO – Research Use Only