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Isopropylmagnesium chloride - LiCl complex, 1M in MeTHF, Thermo Scientific Chemicals
£133.00 - £455.00
Chemical Identifiers
CAS | 807329-97-1 |
---|---|
Molecular Formula | C3H7Cl2LiMg |
Molecular Weight (g/mol) | 145.23 |
MDL Number | MFCD07784514 |
InChI Key | CWTUREABAILGIK-UHFFFAOYSA-L |
Synonym | turbo grignard, iprmgcl licl, i-prmgcl licl, i-prmgcl.licl, isopropylmagnesiumchloride licl, isopropylmagnesium chloride licl, isopropyl magnesium chloride licl, cwtureabailgik-uhfffaoysa-l, isopropylmagnesium lithium chloride, isopropyl magnesium chloride li-cl |
IUPAC Name | lithium(1+) chloro(propan-2-yl)magnesium chloride |
SMILES | [Li+].[Cl-].CC(C)[Mg]Cl |
Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
---|---|---|---|---|---|---|---|---|---|
Product Code | Brand | Quantity | Price | Quantity & Availability | |||||
15449205
|
Thermo Scientific Alfa Aesar
H51156.AE |
100 mL | |||||||
15459205
|
Thermo Scientific Alfa Aesar
H51156.AP |
500 mL |
£455.00
500mL |
Please sign in to purchase this item. Need a web account? Register with us today! | |||||
Description
Isopropylmagnesium chloride is used in the regioselective functionalization of trisubstituted pyridines, electrophilic amination for preparation of amines and functionalization of cyclopentene derivatives. It is involved in the preparation of 2,3-functionalized furans, benzofurans, and thiophenes. Further, it is used in benzylic Grignards via sulfur-magnesium exchange.
This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.
ApplicationsIsopropylmagnesium chloride is used in the regioselective functionalization of trisubstituted pyridines, electrophilic amination for preparation of amines and functionalization of cyclopentene derivatives. It is involved in the preparation of 2,3-functionalized furans, benzofurans, and thiophenes. Further, it is used in benzylic Grignards via sulfur-magnesium exchange.
Solubility
Miscible with ethers and amines.
Notes
Air and moisture sensitive. Incompatible with oxidizing agents and water.
Chemical Identifiers
807329-97-1 | |
145.23 | |
CWTUREABAILGIK-UHFFFAOYSA-L | |
lithium(1+) chloro(propan-2-yl)magnesium chloride |
C3H7Cl2LiMg | |
MFCD07784514 | |
turbo grignard, iprmgcl licl, i-prmgcl licl, i-prmgcl.licl, isopropylmagnesiumchloride licl, isopropylmagnesium chloride licl, isopropyl magnesium chloride licl, cwtureabailgik-uhfffaoysa-l, isopropylmagnesium lithium chloride, isopropyl magnesium chloride li-cl | |
[Li+].[Cl-].CC(C)[Mg]Cl |
Specifications
807329-97-1 | |
−17°C (1.4°F) | |
(CH3)2CHMgCl·LiCl | |
UN3399 | |
turbo grignard, iprmgcl licl, i-prmgcl licl, i-prmgcl.licl, isopropylmagnesiumchloride licl, isopropylmagnesium chloride licl, isopropyl magnesium chloride licl, cwtureabailgik-uhfffaoysa-l, isopropylmagnesium lithium chloride, isopropyl magnesium chloride li-cl | |
CWTUREABAILGIK-UHFFFAOYSA-L | |
lithium(1+) chloro(propan-2-yl)magnesium chloride | |
145.24 | |
Isopropylmagnesium chloride - LiCl complex |
0.951 | |
C3H7Cl2LiMg | |
MFCD07784514 | |
Air and moisture sensitive | |
Miscible with ethers and amines. | |
[Li+].[Cl-].CC(C)[Mg]Cl | |
145.23 | |
1M in MeTHF |
Safety and Handling
GHS H Statement
H225-H261-H314-H318
Highly flammable liquid and vapor.
In contact with water releases flammable gas.
Causes severe skin burns and eye damage.
Causes serious eye damage.
P210-P223-P231+P232-P233-P235-P240-P241-P242-P243-P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P335+P334-P363-P370+P378q-P501c
H225-H260-H302-H314-H335
missing translation for 'dotInformation' : Transport Hazard Class: 4.3; Packing Group: II; Proper Shipping Name: ORGANOMETALLIC SUBSTANCE, LIQUID, WATER-REACTIVE, FLAMMABLE
missing translation for 'tsca' : No
Recommended Storage : Ambient temperatures
RUO – Research Use Only