Lithium borohydride, 4M (10 wt.%) solution in THF, AcroSeal™, Thermo Scientific Chemicals

Product Code	Brand	Quantity	Packaging
10752767	Thermo Scientific Acros 428881000	100 mL	AcroSeal™ Glass Bottle
10159639	Thermo Scientific Acros 428888000	800 mL	AcroSeal™ Glass bottle

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Reduction reagent

Specifications

• CAS: 16949-15-8, 109-99-9
• Linear Formula: LiBH₄
• Flash Point: −21°C
• Synonym: borate 1-, tetrahydro-, lithium, unii-8l87x4s4kp, boryllithium, lithium, boryl, lithium hydroborate, lithotab borohydride, bh4li, lithium 1+ ion boranuide, lithium borohydride 2.0 m in thf, borate 1-, tetrahydro-, lithium 1:1
• InChI Key: UUKMSDRCXNLYOO-UHFFFAOYSA-N
• IUPAC Name: lithium;boron(1-)
• PubChem CID: 20722760
• Specific Gravity: 0.89

• Molecular Formula: BH4Li
• MDL Number: MFCD00011088
• Merck Index: 15,5581
• Solubility Information: Solubility in water: decomposes
• SMILES: [Li+].[BH4-]
• Molecular Weight (g/mol): 21.78
• Formula Weight: 21.77
• Density: 0.8900g/mL

Safety and Handling

GHS H Statement
Highly flammable liquid and vapor.
In contact with water releases flammable gases which may ignite spontaneously.
Harmful if swallowed.
Causes severe skin burns and eye damage.
May cause respiratory irritati

GHS P Statement
Keep away from heat/sparks/open flames/hot surfaces.
- No smoking.
IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with water/shower.
Handle under inert gas.
Protect from moisture

GHS Signal Word: Danger

missing translation for 'einecsNumber' : 241-021-7

Product Identifier

• Lithium borohydride, 4M (10 wt.%) solution in THF

Signal Word

• Danger

Hazard Category

• Acute toxicity Category 4
• Carcinogenicity Category 2
• Serious eye damage/eye irritation Category 1
• Flammable liquid Category 2
• Skin corrosion/irritation Category 1 B
• Specific target organ toxicity Category 3
• Substance which\, in contact with water\, emits flammable gases Category 1

Hazard Statement

• H318-Causes serious eye damage.
• H314-Causes severe skin burns and eye damage.
• H351-Suspected of causing cancer.
• H335-May cause respiratory irritation.
• H336-May cause drowsiness or dizziness.
• H302-Harmful if swallowed.
• H260-In contact with water releases flammable gases which may ignite spontaneously.
• H225-Highly flammable liquid and vapour.
• EUH014-Reacts violently with water.
• EUH019-May form explosive peroxides.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P231+P232-Handle under inert gas. Protect from moisture.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.

RUO – Research Use Only