Phosphorus tribromide, 1.0M solution in dichloromethane, AcroSeal™, Thermo Scientific Chemicals

Product Code	Brand	Quantity	Packaging
10108072	Thermo Scientific Acros 382061000	100 mL	AcroSeal™ Glass bottle
10705993	Thermo Scientific Acros 382068000	800 mL	AcroSeal™ Glass Bottle

Description

This Thermo Scientific Chemicals brand product was originally part of the Acros Organics product portfolio. Some documentation and label information may refer to the legacy brand. The original Acros Organics product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

C-X bond formation reagent

Specifications

• Chemical Name or Material: Phosphorus tribromide
• CAS: 7789-60-8, 75-09-2
• Physical Form: Liquid
• Linear Formula: PBr₂
• Merck Index: 15, 7469
• InChI Key: IPNPIHIZVLFAFP-UHFFFAOYSA-N
• IUPAC Name: tribromophosphane
• PubChem CID: 24614
• Concentration or Composition (by Analyte or Components): 0.9 to 1.1M
• Density: 1.4880g/mL

• Name Note: 1.0M Solution in Dichloromethane
• Color: Colorless to Yellow
• Molecular Formula: Br₃P
• MDL Number: MFCD00011436
• Synonym: phosphorus tribromide, phosphorous tribromide, tribromophosphine, phosphorus iii bromide, phosphorous bromide, pbr3, phosphorus bromide, phosphorus bromide pbr3, unii-58r3866pua, tribro-mophosphine
• SMILES: P(Br)(Br)Br
• Molecular Weight (g/mol): 270.69
• Formula Weight: 270.69
• Specific Gravity: 1.488

Safety and Handling

GHS H Statement
Suspected of causing cancer if inhaled.
Causes severe skin burns and eye damage.
May cause respiratory irritation.
May cause drowsiness or dizziness.
Reacts violently with water.

GHS P Statement
Wear protective gloves/protective clothing/eye protection/face protection.
IF SWALLOWED: rinse mouth.
Do NOT induce vomiting.
IF ON SKIN (or hair): Take off immediately all contaminated clothing.
Rinse skin with wat

GHS Signal Word: Danger

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Product Identifier

• Phosphorus tribromide, 1M solution in dichloromethane

Signal Word

• Danger

Hazard Category

• Carcinogenicity Category 2
• Serious eye damage/eye irritation Category 1
• Skin corrosion/irritation Category 1 B
• Specific target organ toxicity after repeated exposure Category 2
• Specific target organ toxicity Category 3

Hazard Statement

• H318-Causes serious eye damage.
• H351-Suspected of causing cancer.
• H373-May cause damage to organs.
• H335-May cause respiratory irritation.
• H336-May cause drowsiness or dizziness.
• H314-Causes severe skin burns and eye damage.
• EUH014-Reacts violently with water.

Precautionary Statement

• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P301+P330+P331-IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P304+P340-IF INHALED: Remove person to fresh air and keep comfortable for breathing.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.

RUO – Research Use Only