Tris(dimethylamino)aluminum dimer, Thermo Scientific Chemicals

Product Code	Brand	Quantity
11329328	Thermo Scientific Alfa Aesar 043237.03	1 g
11349328	Thermo Scientific Alfa Aesar 043237.06	5 g

Description

Preparation of aluminum nitrides

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

• Packaged under Argon

Chemical Identifiers

• CAS: 32093-39-3
• Molecular Weight (g/mol): 318.425
• InChI Key: JGZUJELGSMSOID-UHFFFAOYSA-N
• PubChem CID: 16688802
• SMILES: CN(C)[Al](N(C)C)N(C)C.CN(C)[Al](N(C)C)N(C)C

• Molecular Formula: C12H36Al2N6
• MDL Number: MFCD00269811
• Synonym: tris dimethylamido aluminum iii, tris dimethylamino aluminum dimer, bis bis dimethylamino alumanyl dimethylamine, bis mu-dimethylamino tetrakis dimethylamino dialuminum
• IUPAC Name: N-[bis(dimethylamino)alumanyl]-N-methylmethanamine

Specifications

• CAS: 32093-39-3
• Color: Brown to White
• Boiling Point: 90°C (0.05 mmHg)(sublimation)
• Molecular Formula: C12H36Al2N6
• MDL Number: MFCD00269811
• Sensitivity: Moisture sensitive
• InChI Key: JGZUJELGSMSOID-UHFFFAOYSA-N
• IUPAC Name: N-[bis(dimethylamino)alumanyl]-N-methylmethanamine
• PubChem CID: 16688802
• Physical Form: Powder

• Melting Point: 87°C to 89°C
• Density: 0.865 g/mL
• Flash Point: 21°C (70°F)
• Linear Formula: Al₂[N(CH₃)₂]₆
• UN Number: UN3131
• Synonym: tris dimethylamido aluminum iii, tris dimethylamino aluminum dimer, bis bis dimethylamino alumanyl dimethylamine, bis mu-dimethylamino tetrakis dimethylamino dialuminum
• SMILES: CN(C)[Al](N(C)C)N(C)C.CN(C)[Al](N(C)C)N(C)C
• Molecular Weight (g/mol): 318.425
• Formula Weight: 318.42
• Chemical Name or Material: Tris (dimethylamino)aluminum dimer

Safety and Handling

GHS H Statement
H228-H260-H314-H318
Flammable solid.
In contact with water releases flammable gases which may ignite spontaneously.
Causes severe skin burns and eye damage.
Causes serious eye damage.

P210-P223-P231+P232-P240-P241-P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P335+P334-P363-P370+P378q-P501c

H228-H260-H314-H335

missing translation for 'dotInformation' : Transport Hazard Class: 4.3; Packing Group: I; Proper Shipping Name: WATER-REACTIVE SOLID, CORROSIVE, N.O.S.

missing translation for 'tsca' : No

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• Packaged under Argon

Recommended Storage : Ambient temperatures

Product Identifier

• Tris(dimethylamino)aluminum dimer

Signal Word

• Danger

Hazard Category

• Flammable liquid Category 1
• Substance which\, in contact with water\, emits flammable gases Category 1
• Skin corrosion/irritation Category 1 B

Hazard Statement

• H280-Contains gas under pressure; may explode if heated.
• H260-In contact with water releases flammable gases which may ignite spontaneously.
• H314-Causes severe skin burns and eye damage.
• EUH014-Reacts violently with water.

Precautionary Statement

• P210-Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
• P280-Wear protective gloves/protective clothing/eye protection/face protection.
• P303+P361+P353-IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/ shower.
• P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
• P310-Immediately call a POISON CENTER/doctor/.
• P402+P404-Store in a dry place. Store in a closed container.

RUO – Research Use Only